1,3-Dithiolane

A common family of 1,3-dithiolanes have the formula . They are obtained by treating an aldehyde with 1,2-ethanedithiol. Related compounds with the formula are obtained by condensation of 1,2-ethanedithiol with ketones. The dithiolane protected aldehydes and ketones are amenable to many reactions without perturbing the dithiolane ring. Dithiolanes can often be reverted, i.e., deprotected, to the parent aldehyde and ketone. A variety of reagents have been developed for that purpose. ==Reactions==

1,3-Dithiolanes derived from aldehydes can be deprotonated: : These organolithium compounds degrade with loss of ethylene to give the dithiocarboxylate: : In contrast, 2-lithio-1,3-dithianes () are long-lived. 1,3-Dithiolanes are susceptible to a variety of degradation processes involving organometallic reagents leading to other organosulfur compounds. ==References==