On 2 December 2024,
Carlos Alcaraz and
Taylor Fritz were the first players to confirm their participation for
Team Europe and
Team World respectively. On 20 February 2025,
Alexander Zverev and
Ben Shelton were the next players to announce their participation.
Tommy Paul was confirmed for the event on 1 April 2025. On 13 May 2025, organizers announced that
Holger Rune and
João Fonseca would make their Laver Cup debuts. On 30 July 2025,
Casper Ruud and on 12 August,
Frances Tiafoe announced their participation in the event. On 19 August 2025, both teams announced their final line-ups. As their final picks, Team Europe captain
Yannick Noah chose
Jakub Menšík and
Flavio Cobolli while Team World captain
Andre Agassi named
Francisco Cerúndolo. On 4 September 2025, Shelton and Paul withdrew due to injuries and were replaced by
Alex Michelsen and
Reilly Opelka. On 12 September 2025, Tiafoe withdrew and was replaced by
Alex de Minaur. On 15 September 2025,
Tomáš Macháč and
Jenson Brooksby were announced as alternates. == Participants ==