•
Lorenzo Barili (26 May 1851 – 17 June 1856) •
Mieczyslaw Halka Ledóchowski (17 June 1856 – 25 July 1861) •
Francesco Tavani (25 July 1861 – 18 July 1869) •
Serafino Vannutelli (23 July 1869 – 15 March 1875) •
Mario Mocenni (6 August 1877 – 27 February 1882) •
Cesare Sambucetti (30 March 1882 – 1883) •
Beniamino Cavicchioni (21 March 1884 – 4 August 1889) •
José Macchi (12 April 1889 – 2 August 1897) •
Pietro Gasparri (18 December 1897 – 23 April 1901) •
Alessandro Bavona (13 July 1901 – 13 November 1906) •
Fernando Cento (6 August 1937 – 26 November 1937) •
Efrem Forni (26 November 1937 – 9 November 1953) •
Opilio Rossi (21 November 1953 – 25 March 1959) •
Alfredo Bruniera (25 April 1959 – 23 October 1965) •
Giovanni Ferrofino (3 November 1965 – 29 September 1970) •
Luigi Accogli (29 September 1970 – 6 July 1979) •
Vincenzo Maria Farano (25 August 1979 – 14 August 1986) •
Luigi Conti (17 January 1987 – 12 April 1991) •
Francesco Canalini (20 July 1991 – 5 December 1998) •
Alain Paul Charles Lebeaupin (7 December 1998 – 14 January 2005) •
Giacomo Guido Ottonello (26 February 2005 – 1 April 2017) •
Andrés Carrascosa Coso (22 June 2017 – 11 December 2025) •
Dagoberto Campos Salas (1 May 2026 – present) ==References==