Most of the BESS systems are composed of securely sealed
battery packs, which are electronically monitored and replaced once their performance falls below a given threshold. Batteries suffer from cycle ageing, or deterioration caused by charge–discharge cycles. This deterioration is generally higher at
high charging rates and higher
depth of discharge. This aging causes a loss of performance (capacity or voltage decrease), overheating, and may eventually lead to critical failure (electrolyte leaks, fire, explosion). Sometimes battery storage power stations are built with
flywheel storage power systems in order to conserve battery power. Flywheels may handle rapid fluctuations better than older battery plants. BESS
warranties typically include lifetime limits on energy throughput, expressed as number of charge–discharge cycles.
Lead-acid based batteries Lead-acid batteries, as a first-generation technology, are generally used in older BESS systems. Some examples are 1.6 MW peak, 1.0 MW continuous battery was commissioned in 1997. Compared to modern rechargeable batteries, lead-acid batteries have relatively low
energy density. Despite this, they are able to supply high
surge currents. However, non-sealed
lead-acid batteries produce hydrogen and oxygen from the aqueous electrolyte when overcharged. The water has to be refilled regularly to avoid damage to the battery; and, the inflammable gases have to be vented out to avoid explosion risks. However, this maintenance has a cost, and recent batteries such as
Li-ion batteries do not have such an issue.
Lithium-based batteries Lithium-ion batteries offer a long lifespan with minimal maintenance, high energy density, and low
self-discharge, which makes them ideal for modern utility-scale BESS applications. A drawback of some types of lithium-ion batteries is fire safety, mostly ones containing cobalt. The number of BESS incidents has remained around 10–20 per year (mostly within the first 2–3 years of age), despite the large increase in number and size of BESS. Thus
failure rate has decreased. Failures occurred mostly in controls and
balance of system, while 11% occurred in cells. Examples of BESS fire accidents include individual modules in 23 battery farms in
South Korea in 2017 to 2019, a
Tesla Megapack in
Geelong, the fire and subsequent explosion of a battery module in
Arizona, This resulted in more research in recent years for mitigation measures for fire safety. By 2024, the
lithium iron phosphate (LFP) battery has become another significant type for large storages due to the high availability of its components,
longer lifetime and higher safety compared to nickel-based Li-ion chemistries. An LFP-based energy storage system that was installed in
Paiyun Lodge on
Mt. Jade (Yushan) (the highest alpine lodge in
Taiwan) and operated since 2016 without a safety incident.
Sodium-based batteries Alternatively,
sodium-based batteries are increasingly being considered for BESS applications. Compared to lithium-ion batteries, sodium-ion batteries have somewhat lower cost, better safety characteristics, and similar power delivery characteristics. However it has a lower energy density compared to lithium-ion batteries. Its
working principle and
cell construction are similar to those of
lithium-ion battery (LIB) types, but it replaces
lithium with
sodium as the
intercalating ion. Some sodium-based batteries can also operate safely at high temperatures (
sodium–sulfur battery). Some notable sodium battery producers with high safety claims include (non-exclusive) Altris AB, SgNaPlus and Tiamat. Sodium-based batteries are not fully commercialised yet. The largest BESS utilizing sodium-ion technology started operating in 2024 in Hubei province, boasts a capacity of 50 MW / 100 MWh. == Operating characteristics ==