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Blast furnace

A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. Blast refers to the combustion air being supplied above atmospheric pressure.

Process engineering and chemistry
in Czech Republic , 1923 reduces iron oxides to pure iron through a series of reactions that occur at different areas within a blast furnace. Blast furnaces operate on the principle of chemical reduction whereby carbon monoxide converts iron oxides to elemental iron. Blast furnaces differ from bloomeries and reverberatory furnaces in that in a blast furnace, flue gas is in direct contact with the ore and iron, allowing carbon monoxide to diffuse into the ore and reduce the iron oxide. The blast furnace operates as a countercurrent exchange process whereas a bloomery does not. Another difference is that bloomeries operate as a batch process whereas blast furnaces operate continuously for long periods. Continuous operation is also preferred because blast furnaces are difficult to start and stop. Also, the carbon in pig iron lowers the melting point below that of steel or pure iron; in contrast, iron does not melt in a bloomery. Silica has to be removed from the pig iron. It reacts with calcium oxide (burned limestone) and forms silicates, which float to the surface of the molten pig iron as slag. Historically, iron was produced with charcoal to prevent sulfur contamination. In a blast furnace, a downward-moving column of ore, flux, coke (or charcoal The main chemical reaction producing the molten iron is: :Fe2O3 + 3CO → 2Fe + 3CO2 This reaction might be divided into multiple steps, with the first being that preheated air blown into the furnace reacts with the carbon in the form of coke to produce carbon monoxide and heat: :2 C(s) + O2(g) → 2 CO(g) Hot carbon monoxide is the reducing agent for the iron ore and reacts with the iron oxide to produce molten iron and carbon dioxide. Depending on the temperature in the different parts of the furnace (warmest at the bottom) the iron is reduced in several steps. At the top, where the temperature usually is in the range between 200 °C and 700 °C, the iron oxide is partially reduced to iron(II,III) oxide, Fe3O4. :3 Fe2O3(s) + CO(g) → 2 Fe3O4(s) + CO2(g) As the iron(II) oxide moves down to the area with higher temperatures, ranging up to 1200 °C degrees, it is reduced further to iron metal: :FeO(s) + CO(g) → Fe(s) + CO2(g) In a further process step, the so-called basic oxygen steelmaking, the carbon is oxidized by blowing oxygen onto the liquid pig iron to form crude steel. ==History==
History
s from the Nong Shu, by Wang Zhen in 1313 during China's Yuan dynasty '', 1637 Cast iron has been found in China dating to the 5th century BC, but the earliest extant blast furnaces in China date to the 1st century AD and in the West from the High Middle Ages. They spread from the region around Namur in Wallonia (Belgium) in the late 15th century, being introduced to England in 1491. The fuel used in these was invariably charcoal. The successful substitution of coke for charcoal is widely attributed to British inventor Abraham Darby in 1709. The efficiency of the process was further enhanced by the practice of preheating the combustion air (hot blast), patented by British inventor James Beaumont Neilson in 1828. China Archaeological evidence shows that iron-smelting techniques and bloomeries were brought to China by nomadic peoples around 800 BC. Wrought iron artifacts were originally only found in the northwest, but by the 6th century BC, luxury items such as wrought iron swords and knives were widespread in China. Bloomery iron co-existed with blast furnaces and cast iron, which were invented shortly after wrought iron technology entered China, for quite some time. Cast iron pieces have been found alongside wrought iron in Shanxi Province dating to the 9th-8th centuries BC, however it is uncertain if these cast iron pieces were accidental byproducts of the iron smelting process. Adzes made using cast iron with a decarburised layer of steel have been found in Luoyang dating to the 5th century BC. Cast iron farming tools that had undergone an annealing process to decrease brittleness were found in burials and smelting cites dating to the 4th century BC. Bloomery iron disappeared in China after the 3rd century AD with the exception of Xinjiang, where bloomery iron objects could be found as late as the 9th century AD. In China, blast furnaces produced cast iron, which was then either converted into finished implements in a cupola furnace, or turned into wrought iron in a fining hearth. employing workforces of over 200 men in iron smelters from the 3rd century onward, the earliest blast furnaces constructed were attributed to the Han dynasty in the 1st century AD. These early furnaces had clay walls and used phosphorus-containing minerals as a flux. Chinese blast furnaces ranged from around two to ten meters in height, depending on the region. The largest ones were found in modern Sichuan and Guangdong, while the 'dwarf" blast furnaces were found in Dabieshan. In construction, they are both around the same level of technological sophistication. The effectiveness of the Chinese human and horse powered blast furnaces was enhanced during this period by the engineer Du Shi (c. AD 31), who applied the power of waterwheels to piston-bellows in forging cast iron. Early water-driven reciprocators for operating blast furnaces were built according to the structure of horse powered reciprocators that already existed. That is, the circular motion of the wheel, be it horse driven or water driven, was transferred by the combination of a belt drive, a crank-and-connecting-rod, other connecting rods, and various shafts, into the reciprocal motion necessary to operate push bellows. Donald Wagner suggests that early blast furnace and cast iron production evolved from furnaces used to melt bronze. Certainly, though, iron was essential to military success by the time the State of Qin had unified China (221 BC). Usage of the blast and cupola furnace remained widespread during the Song and Tang dynasties. By the 11th century, the Song dynasty Chinese iron industry made a switch of resources from charcoal to coke in casting iron and steel, sparing thousands of acres of woodland from felling. This may have happened as early as the 4th century AD. The primary advantage of the early blast furnace was in large scale production and making iron implements more readily available to peasants. Cast iron is more brittle than wrought iron or steel, which required additional fining and then cementation or co-fusion to produce, but for menial activities such as farming it sufficed. By using the blast furnace, it was possible to produce larger quantities of tools such as ploughshares more efficiently than the bloomery. In areas where quality was important, such as warfare, wrought iron and steel were preferred. Nearly all Han period weapons are made of wrought iron or steel, with the exception of axe-heads, of which many are made of cast iron. Blast furnaces were also later used to produce gunpowder weapons such as cast iron bomb shells and cast iron cannons during the Song dynasty. Medieval Europe The simplest forge, known as the Corsican. Examples of improved bloomeries are the Stuckofen, sometimes called wolf-furnace, which remained until the beginning of the 19th century. Instead of using natural draught, air was pumped in by a trompe, resulting in better quality iron and an increased capacity. This pumping of air in with bellows is known as cold blast, and it increases the fuel efficiency of the bloomery and improves yield. They can also be built bigger than natural draught bloomeries. Oldest European blast furnaces The oldest known blast furnaces in the West were built in Durstel in Switzerland, the Märkische Sauerland in Germany, and at Lapphyttan in Sweden, where the complex was active between 1205 and 1300. At Noraskog in the Swedish parish of Järnboås, traces of even earlier blast furnaces have been found, possibly from around 1100. These early blast furnaces, like the Chinese examples, were very inefficient compared to those used today. The iron from the Lapphyttan complex was used to produce balls of wrought iron known as osmonds, and these were traded internationally – a possible reference occurs in a treaty with Novgorod from 1203 and several certain references in accounts of English customs from the 1250s and 1320s. Other furnaces of the 13th to 15th centuries have been identified in Westphalia. The technology required for blast furnaces may have either been transferred from China, or may have been an indigenous innovation. Al-Qazvini in the 13th century and other travellers subsequently noted an iron industry in the Alburz Mountains to the south of the Caspian Sea. This is close to the silk route, so that the use of technology derived from China is conceivable. Much later descriptions record blast furnaces about three metres high. As the Varangian Rus' people from Scandinavia traded with the Caspian (using their Volga trade route), it is possible that the technology reached Sweden by this means. The Vikings are known to have used double bellows, which greatly increases the volumetric flow of the blast. The Caspian region may also have been the source for the design of the furnace at Ferriere, described by Filarete, involving a water-powered bellows at Semogo in Valdidentro in northern Italy in 1226. In a two-stage process the molten iron was tapped twice a day into water, thereby granulating it. Cistercian contributions The General Chapter of the Cistercian monks spread some technological advances across Europe. This may have included the blast furnace, as the Cistercians are known to have been skilled metallurgists. According to Jean Gimpel, their high level of industrial technology facilitated the diffusion of new techniques: "Every monastery had a model factory, often as large as the church and only several feet away, and waterpower drove the machinery of the various industries located on its floor." Iron ore deposits were often donated to the monks along with forges to extract the iron, and after a time surpluses were offered for sale. The Cistercians became the leading iron producers in Champagne, France, from the mid-13th century to the 17th century, also using the phosphate-rich slag from their furnaces as an agricultural fertilizer. Archaeologists are still discovering the extent of Cistercian technology. At Laskill, an outstation of Rievaulx Abbey and the only medieval blast furnace so far identified in Britain, the slag produced was low in iron content. Slag from other furnaces of the time contained a substantial concentration of iron, whereas Laskill is believed to have produced cast iron quite efficiently. Its date is not yet clear, but it probably did not survive until Henry VIII's Dissolution of the Monasteries in the late 1530s, as an agreement (immediately after that) concerning the "smythes" with the Earl of Rutland in 1541 refers to blooms. Nevertheless, the means by which the blast furnace spread in medieval Europe has not finally been determined. Origin and spread of early modern blast furnaces Due to the increased demand for iron for casting cannons, the blast furnace came into widespread use in France in the mid 15th century. The direct ancestor of those used in France and England was in the Namur region, in what is now Wallonia (Belgium). From there, they spread first to the Pays de Bray on the eastern boundary of Normandy and from there to the Weald of Sussex, where the first furnace (called Queenstock) in Buxted was built in about 1491, followed by one at Newbridge in Ashdown Forest in 1496. They remained few in number until about 1530 but many were built in the following decades in the Weald, where the iron industry perhaps reached its peak about 1590. Most of the pig iron from these furnaces was taken to finery forges for the production of bar iron. The first British furnaces outside the Weald appeared during the 1550s, and many were built in the remainder of that century and the following ones. The output of the industry probably peaked about 1620, and was followed by a slow decline until the early 18th century. This was apparently because it was more economic to import iron from Sweden and elsewhere than to make it in some more remote British locations. Charcoal that was economically available to the industry was probably being consumed as fast as the wood to make it grew. The first blast furnace in Russia opened in 1637 near Tula and was called the Gorodishche Works. The blast furnace spread from there to central Russia and then finally to the Urals. Coke blast furnaces in Madeley, England , 1930 first commissioned in 1715 by order of Peter the Great with the help of Holland masters. In 1709, at Coalbrookdale in Shropshire, England, Abraham Darby began to fuel a blast furnace with coke instead of charcoal. Coke's initial advantage was its lower cost, mainly because making coke required much less labor than cutting trees and making charcoal, but using coke also overcame localized shortages of wood, especially in Britain and elsewhere in Europe. Metallurgical grade coke will bear heavier weight than charcoal, allowing larger furnaces. A disadvantage is that coke contains more impurities than charcoal, with sulfur being especially detrimental to the iron's quality. Coke's impurities were more of a problem before hot blast reduced the amount of coke required and before furnace temperatures were hot enough to make slag from limestone free flowing. (Limestone ties up sulphur. Manganese may also be added to tie up sulphur.) Coke iron was initially only used for foundry work, making pots and other cast iron goods. Foundry work was a minor branch of the industry, but Darby's son built a new furnace at nearby Horsehay, and began to supply the owners of finery forges with coke pig iron for the production of bar iron. Coke pig iron was by this time cheaper to produce than charcoal pig iron. The use of a coal-derived fuel in the iron industry was a key factor in the British Industrial Revolution. However, in many areas of the world charcoal was cheaper while coke was more expensive even after the Industrial Revolution: e. g., in the US charcoal-fueled iron production fell in share to about a half but still continued to increase in absolute terms until , while in João Monlevade in the Brazilian Highlands charcoal-fired blast furnaces were built as late as the 1930s and only phased out in 2000. Darby's original blast furnace has been archaeologically excavated and can be seen in situ at Coalbrookdale, part of the Ironbridge Gorge Museums. Cast iron from the furnace was used to make girders for the world's first cast iron bridge in 1779. The Iron Bridge crosses the River Severn at Coalbrookdale and remains in use for pedestrians. (1794-), depicted in a miniature in the Deutsches Museum Steam-powered blast The steam engine was applied to power blast air, overcoming a shortage of water power in areas where coal and iron ore were located. This was first done at Coalbrookdale where a steam engine replaced a horse-powered pump in 1742. Such engines were used to pump water to a reservoir above the furnace. The first engines used to blow cylinders directly was supplied by Boulton and Watt to John Wilkinson's New Willey Furnace. This powered a cast iron blowing cylinder, which had been invented by his father Isaac Wilkinson. He patented such cylinders in 1736, to replace the leather bellows, which wore out quickly. Isaac was granted a second patent, also for blowing cylinders, in 1757. The steam engine and cast iron blowing cylinder led to a large increase in British iron production in the late 18th century. Hot blast was patented by James Beaumont Neilson at Wilsontown Ironworks in Britain in 1828. Within a few years of the introduction, hot blast was developed to the point where fuel consumption was cut by one-third using coke or two-thirds using coal, while furnace capacity was also significantly increased. Within a few decades, the practice was to have a "stove" as large as the furnace next to it into which the waste gas (containing CO) from the furnace was directed and burnt. The resultant heat was used to preheat the air blown into the furnace. Hot blast enabled the use of raw anthracite coal, which was difficult to light, in the blast furnace. Anthracite was first tried successfully by George Crane at Ynyscedwyn Ironworks in south Wales in 1837. It was taken up in America by the Lehigh Crane Iron Company at Catasauqua, Pennsylvania, in 1839. Anthracite use declined when very high capacity blast furnaces requiring coke were built in the 1870s. ==Modern applications of the blast furnace==
Modern applications of the blast furnace
Iron blast furnaces The blast furnace remains an important part of modern iron production. Modern furnaces are highly efficient, including Cowper stoves to pre-heat the blast air and employ recovery systems to extract the heat from the hot gases exiting the furnace. Competition in industry drives higher production rates. The largest blast furnace in the world is in South Korea, with a volume around . It can produce around of iron per year. This is a great increase from the typical 18th-century furnaces, which averaged about per year. Variations of the blast furnace, such as the Swedish electric blast furnace, have been developed in countries which have no native coal resources. According to Global Energy Monitor, the blast furnace is likely to become obsolete to meet climate change objectives of reducing carbon dioxide emission, but BHP disagrees. but this also needs to use a blast furnace to melt the iron and remove the gangue (impurities) unless the ore is very high quality. Oxygen blast furnace The oxygen blast furnace (OBF) process, developed from the 1970s to the 1990s, has been extensively studied theoretically because of the potentials of promising energy conservation and emission reduction. This type may be the most suitable for use with CCS. Blast furnaces in copper and lead smelting Blast furnaces are currently rarely used in copper smelting, but modern lead smelting blast furnaces are much shorter than iron blast furnaces and are rectangular in shape. Modern lead blast furnaces are constructed using water-cooled steel or copper jackets for the walls, and have no refractory linings in the side walls. The base of the furnace is a hearth of refractory material (bricks or castable refractory). The blast furnace used at the Nyrstar Port Pirie lead smelter differs from most other lead blast furnaces in that it has a double row of tuyeres rather than the single row normally used. This is because the zinc produced by these furnaces is recovered as metal from the vapor phase, and the presence of oxygen in the off-gas would result in the formation of zinc oxide. However, ISP furnaces have the advantage of being able to treat zinc concentrates containing higher levels of lead than can electrolytic zinc plants. Very small amounts of metals are also produced which are an unwanted by-product. ==Modern iron process==
Modern iron process
Modern furnaces are equipped with an array of supporting facilities to increase efficiency, such as ore storage yards where barges are unloaded. The raw materials are transferred to the stockhouse complex by ore bridges, or rail hoppers and ore transfer cars. Rail-mounted scale cars or computer controlled weight hoppers weigh out the various raw materials to yield the desired hot metal and slag chemistry. The raw materials are brought to the top of the blast furnace via a skip car powered by winches or conveyor belts. There are different ways in which the raw materials are charged into the blast furnace. Some blast furnaces use a "double bell" system where two "bells" are used to control the entry of raw material into the blast furnace. The purpose of the two bells is to minimize the loss of hot gases in the blast furnace. First, the raw materials are emptied into the upper or small bell which then opens to empty the charge into the large bell. The small bell then closes, to seal the blast furnace, while the large bell rotates to provide specific distribution of materials before dispensing the charge into the blast furnace. A more recent design is to use a "bell-less" system. These systems use multiple hoppers to contain each raw material, which is then discharged into the blast furnace through valves. The iron making blast furnace itself is built in the form of a tall structure, lined with refractory brick, and profiled to allow for expansion of the charged materials as they heat during their descent, and subsequent reduction in size as melting starts to occur. Coke, limestone flux, and iron ore (iron oxide) are charged into the top of the furnace in a precise filling order which helps control gas flow and the chemical reactions inside the furnace. Four "uptakes" allow the hot, dirty gas high in carbon monoxide content to exit the furnace throat, while "bleeder valves" protect the top of the furnace from sudden gas pressure surges. The coarse particles in the exhaust gas settle in the "dust catcher" and are dumped into a railroad car or truck for disposal, while the gas itself flows through a venturi scrubber and/or electrostatic precipitators and a gas cooler to reduce the temperature of the cleaned gas. Shaped like an inverted, truncated cone, it is the part of the blast furnace where ore turns molten. Next is the bustle pipe (a large-diameter annular pipe to deliver heated air under pressure to the tuyeres) and the equipment for casting the liquid iron and slag. Once a "taphole" is drilled through the refractory clay plug, liquid iron and slag flow down a trough through a "skimmer" opening, separating the iron and slag. Modern, larger blast furnaces may have as many as four tapholes and two casthouses. Waste heat is usually collected from the exhaust gases, for example by the use of a Cowper stove, a variety of heat exchanger. ==Environmental impact==
Environmental impact
Fossil fuel (coke, natural gas) use in blast furnaces is a source of greenhouse gas emissions and the blast furnace is the most emission intensive stage of the steel making process. Fuels and reductants such as plastic waste, biomass and hydrogen are being used by steelmakers as possible alternatives to fossil fuels, although cost and availability remain a challenge and deployment is limited. Electric arc furnaces (EAF) are cited as an alternative steel production path which avoids the use of blast furnaces, however, depending on the characteristics of the steel product required the two furnace types are not always interchangeable. Furthermore, EAFs utilize steel scrap as a feedstock but estimates suggest that there will not be enough scrap available to meet future steel demand. Using hydrogen gas as a reductant to produce DRI (so called H2-DRI) from iron ore, which is then used as a feedstock for an EAF provides a technologically feasible, low emission alternative to blast furnaces. ULCOS (Ultra Low CO2 Steelmaking) was a European programme exploring processes to reduce blast furnace emissions by at least 50%. Technologies identified include carbon capture and storage (CCS) and alternative energy sources and reductants such as hydrogen, electricity and biomass. Carbon capture, utilisation, and storage (CCUS) For existing blast furnaces, carbon capture, utilisation, and storage (CCUS) is a potential solution to abate emissions. This involves capturing CO2 from the furnace's waste gases before they are released, and then either transporting it for permanent underground storage (CCS) or using it to create other products (CCU).{{Cite journal|title=Retrofitting Blast Furnaces for Producing Green Steel and Green Urea|url=https://www.ijee.latticescipub.com/wp-content/uploads/papers/v5i2/B187105021125.pdf ==Preserved historic blast furnaces==
Preserved historic blast furnaces
Historically it was normal procedure for a decommissioned blast furnace to be demolished and either replaced with a newer, improved one, or to have the entire site demolished and treated for follow-up use of the area. In recent decades, several countries have realized the historic value of blast furnaces and have transformed them into museums. Examples can be found in the Czech Republic, France, Germany, Japan, Luxembourg, Poland, Romania, Mexico, Russia, Spain, United Kingdom, and United States. ==Gallery==
Gallery
File:Alto horno antiguo Sestao.jpg|Abandoned blast furnace in Sestao, Spain. The furnace itself is inside the central girderwork. File:Old blast furnace gas cleaning plant 2012-05-02.jpg|Part of the gas cleaning system of a blast furnace in Monclova, Mexico. This one is about to be de-commissioned and replaced. ==See also==
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