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Carbon nanofoam

Carbon nanofoam is an allotrope of carbon discovered in 1997 by Andrei V. Rode and co-workers at the Australian National University in Canberra. It consists of a cluster-assembly of carbon atoms strung together in a loose three-dimensional web. The fractal-like bond structure consists of sp2 graphite-like clusters connected by sp3 bonds. The sp3 bonds are located mostly on the surface of the structure and make up 15% to 45% of the material, making its framework similar to diamond-like carbon films. The material is remarkably light, with a density of 2-10 × 10−3 g/cm3 (0.0012 lb/ft3) and is similar to an aerogel. Other remarkable physical properties include the large surface area of 300–400 m2/g. 1 US gallon of nanofoam weighs about 0.25 ounces (7.1 g).

Synthesis
Carbon nanofoam clusters can be synthesized through high-repetition-rate laser ablation in inert gases such as argon. Short (fs), low-energy (μJ) pulses delivered at high rates of repetition (10 kHz – 100 MHz) generate carbon vapors for deposition. Ambient gas is heated from room temperature with the atomized carbon which leads to an increase in the partial density of the carbon in the chamber. In optimal conditions, the inert gas does not cool down but maintains its high temperature between cycles of formation. Subsequent cycles in the chamber are carried out at temperatures above the formation threshold temperature initiating sp2 bonding. The increase in density and temperature promotes favorable conditions for the formation of carbonaceous clusters. The rate of consumption exceeds the rate of evaporation by laser ablation and thus the formation is in a non-equilibrium state. ==See also==
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