Charles married three times; firstly to Countess Anne Élisabeth de
Lannoy (1626–1654), daughter of Count Charles de Lannoy; the couple married on 7 March 1648; •
Anne Élisabeth of Lorraine (6 August 1649 – 5 August 1714) known as ''Mademoiselle d'Elbeuf'', she married
Charles Henri de Lorraine, a distant cousin and illegitimate son of
Charles IV, Duke of Lorraine, and had issue:
Charles Thomas, Prince of Vaudémont. • Charles of Lorraine, Chevalier d'Elboeuf (2 November 1650 – 1690), never married; Secondly Charles married Princess Élisabeth de
La Tour d'Auvergne (daughter of the
Duke of Bouillon and sister of
Godefroy Maurice de La Tour d'Auvergne) on 20 May 1656 and had six children; • Henri Frédéric of Lorraine, Count of Islebonne (26 January 1657 – 21 October 1666) died in infancy; • Marie Eléonore of Lorraine (24 February 1658 – March 1731), Abbess of Saint Jacques; • Marie Françoise de Lorraine (5 May 1659 – ?), Abbess of Saint Germaine; •
Henri of Lorraine, Duke of Elbeuf (7 August 1661 – 17 May 1748) married Charlotte de
Rochechouart de Mortemart, daughter of
Louis Victor de Rochechouart de Mortemart, niece of
Madame de Montespan and had issue; • Louis of Lorraine, Abbot of Orcamp (18 September 1662 – 4 February 1693) had illegitimate issue; •
Emmanuel Maurice of Lorraine, Duke of Elbeuf (30 December 1677 – 17 July 1763), married twice but no issue; at his death the
Duchy of Elbeuf went to
Charles Eugène de Lorraine,
prince de Lambesc; Thirdly, Charles married Françoise de
Montault de Navailles, daughter of
Philippe de Montaut-Bénac, Duke de Navailles, on 25 August 1684; •
Suzanne Henriette of Lorraine (1 February 1686 – 19 October 1710) married
Ferdinand Charles, Duke of Mantua and Montferrat, no issue; • Louise Anne of Lorraine, Princess of Navailles (10 July 1689 – 1762) never married. Charles also had three illegitimate children, including
Charles bâtard de Lorraine (1645–1708), no surviving issue. ==Ancestry==