In quantum mechanics each measurable physical quantity of a quantum system is called an
observable which, for example, could be the position r and the momentum p but also energy E, z components of spin (s_{z}), and so on. The observable acts as a
linear function on the states of the system; its eigenvectors correspond to the quantum state (i.e.
eigenstate) and the
eigenvalues to the possible values of the observable. The collection of eigenstates/eigenvalue pairs represent all possible values of the observable. Writing \phi_i for an eigenstate and c_i for the corresponding observed value, any arbitrary state of the quantum system can be expressed as a vector using
bra–ket notation: | \psi \rangle = \sum_i c_i | \phi_i \rangle. The kets \{| \phi_i \rangle\} specify the different available quantum "alternatives", i.e., particular quantum states. The
wave function is a specific representation of a quantum state. Wave functions can therefore always be expressed as eigenstates of an observable though the converse is not necessarily true.
Collapse To account for the experimental result that repeated measurements of a quantum system give the same results, the theory postulates a "collapse" or "reduction of the state vector" upon observation, abruptly converting an arbitrary state into a single component eigenstate of the observable: : | \psi \rangle = \sum_i c_i | \phi_i \rangle \mapsto where the arrow represents a measurement of the observable corresponding to the \phi basis. For any single event, only one eigenvalue is measured, chosen randomly from among the possible values.
Meaning of the expansion coefficients The
complex coefficients \{c_{i}\} in the expansion of a quantum state in terms of eigenstates \{| \phi_i \rangle\}, | \psi \rangle = \sum_i c_i | \phi_i \rangle. can be written as an (complex) overlap of the corresponding eigenstate and the quantum state: c_i = \langle \phi_i | \psi \rangle . They are called the
probability amplitudes. The
square modulus |c_{i}|^{2} is the probability that a measurement of the observable yields the eigenstate | \phi_i \rangle. The sum of the probability over all possible outcomes must be one: :\langle \psi|\psi \rangle = \sum_i |c_i|^2 = 1. As examples, individual counts in a
double slit experiment with electrons appear at random locations on the detector; after many counts are summed the distribution shows a wave interference pattern. In a
Stern-Gerlach experiment with silver atoms, each particle appears in one of two areas unpredictably, but the final conclusion has equal numbers of events in each area. This statistical aspect of quantum measurements differs fundamentally from
classical mechanics. In quantum mechanics the only information we have about a system is its wave function and measurements of its wave function can only give statistical information. ==Terminology==