MarketDihomo-γ-linolenic acid
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Dihomo-γ-linolenic acid

Dihomo-γ-linolenic acid is a 20-carbon ω−6 fatty acid. DGLA is a carboxylic acid with a 20-carbon chain and three cis double bonds; the first double bond is located at the sixth carbon from the omega end. DGLA is the elongation product of γ-linolenic acid. GLA, in turn, is a desaturation product of linoleic acid. DGLA is made in the body by the elongation of GLA, by an efficient enzyme which does not appear to suffer any form of (dietary) inhibition. DGLA is an extremely uncommon fatty acid, found only in trace amounts in animal products.

Biological effects
The eicosanoid metabolites of DGLA are: • Series-1 thromboxanes (thromboxanes with 1 double-bond), via the COX-1 and COX-2 pathways. • Series-1 prostanoids, via the COX-1 and COX-2 pathways. • A 15-hydroxyl derivative that blocks the transformation of arachidonic acid to leukotrienes. All of these effects are anti-inflammatory. This is in marked contrast with the analogous metabolites of arachidonic acid (AA), which are the series-2 thromboxanes and prostanoids and the series-4 leukotrienes. In addition to yielding anti-inflammatory eicosanoids, DGLA competes with AA for COX and lipoxygenase, inhibiting the production of AA's eicosanoids. However, DGLA is converted to AA by Δ5 desaturase (FADS1). FADS1 and ELOVL5 are differently expressed among tissues and cell types. For example, human neutrophils contain ELOVL5 but not FADS1. is a rich source of γ-linolenic acid (GLA)—the dietary precursor to DGLA. Supplementing dietary GLA increases serum DGLA as well as serum AA levels. Cosupplementation of GLA and EPA (20:5 n−3) increases serum DGLA while also decreasing increasing AA levels by blocking Δ5-desaturase activity. Leukotriene synthesis in neutrophils is consequently lowered. Cosupplementation of GLA with botanical n-3 fatty acids also result in improved conversion from GLA to DGLA and reduced conversion from DGLA to AA. == See also ==
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