References to a dividing line between metals and nonmetals appear in the literature as far back as at least 1869. In 1891, Walker published a periodic "tabulation" with a diagonal straight line drawn between the metals and the nonmetals. In 1906,
Alexander Smith published a periodic table with a zigzag line separating the nonmetals from the rest of elements, in his highly influential textbook
Introduction to General Inorganic Chemistry. In 1923, Horace G. Deming, an American chemist, published short (Mendeleev style) and medium (18-column) form periodic tables. Each one had a regular stepped line separating metals from nonmetals. Merck and Company prepared a handout form of Deming's 18-column table, in 1928, which was widely circulated in American schools. By the 1930s Deming's table was appearing in handbooks and encyclopaedias of chemistry. It was also distributed for many years by the Sargent-Welch Scientific Company. ==Double line variant==