Haidinger's scientific work became increasingly concentrated on the phenomenon of "pseudomorphosis", that is, minerals that have taken up the outer aspect of another mineral. For example,
anhydrite would have changed into
gypsum, but the original cleavage planes and crystal habitus would give the impression of anhydrite. Another example given by Haidinger was that of calcium carbonate, which would readily change into calcium magnesium carbonate (
dolomite). In his own words: ... part of the carbonate of lime is replaced by carbonate of magnesia, so as to form in the new species a compound of one atom each. How this change was brought about, is a difficult question to resolve, though the fact cannot be doubted, as we have in the specimen described a demonstration of it, approaching in certainty almost to ocular evidence. To geologists, Haidinger is known especially for his postulate of the "
dolomitization" reaction that would change calcium carbonate into dolomite at low temperatures (below 100 °C). A solution of
magnesium sulfate would convert
calcium carbonate into
dolomite plus
calcium sulfate in solution. Nonetheless in 1844, Haidinger related how his friends, well-known chemists
Friedrich Wöhler,
Eilhard Mitscherlich, and
Leopold Gmelin, had explained to him that powdered dolomite will react, even at room temperature, with a solution of calcium sulfate to give
calcium carbonate plus a solution of magnesium sulfate. (
Durch meinem verehrten Freund Wöhler wurde ich auf die Beobachtung, die auch Mitscherlich und L. Gmelin anführen, aufmerksam gemacht, daß man Dolomit in Pulverform künstlich zerlegen kann, wenn man eine Auflösung von Gyps durch denselben dringen läßt. Bittersalz wird gebildet und kohlensaurer Kalk bleibt zurück. Dieser Versuch erläutert wohle mit hinreichender Evidenz die Bildung des Kalkspathes aus Dolomit bei unserer gewöhnlichen Temperatur und atmosphärischer Pressung: Haidinger, 1844, p. 250.) Haidinger's employee at the
Kaiserlich-Königlichen Hofkammer im Münz- und Bergwesen,
Adolph von Morlot, undertook to investigate the formation of dolomite in the laboratory (no doubt at the request of Haidinger). The outcome of the experiments confirmed what Friedrich Wöhler had predicted in 1843; dolomite does not form from calcium carbonate plus a solution of magnesium sulfate unless high temperatures (more than 200°
Reamur = 250 °C) and high pressures were applied. Von Morlot used
calcite powder soaked in a concentrated solution of magnesium sulfate sealed in a glass tube. Heating the glass tube in an oil bath increased the pressure inside it to at least 15 bar. The glass tube was able to withstand this high pressure only because it had been placed inside a gun barrel filled with sand. In this way, Von Morlot in 1847 had clearly demonstrated the existence of a minimum temperature for the synthesis of the mineral dolomite. When Von Morlot (1847 A) reacted dolomite powder with a concentrated solution of calcium sulfate at room temperature, the result was (solid) calcium carbonate plus a solution of magnesium sulfate. (''Wenn man nämlich durch gepulverten Dolomit eine Auflösung von Gyps filtriert, so entsteht die umgekehrte doppelte Zersetzung in der Art, daß Bittersalz aufgelöst durch's Filtrum geht, während kohlensaurer Kalk zurück bleibt'': Von Morlot, 1847 A, p. 309.) ==Moral standards==