In
The Hague, De Neve joined football club
Quick. When he joined the
Royal Netherlands Army, he started to play football for
Velocitas Breda, which was affiliated with the
Royal Military Academy of the Netherlands. He moved to
HBS Craeyenhout in 1905, and won the
Dutch national football title in his first season back in
The Hague. De Neve was part of the first
Netherlands national team, which played for the
Coupe Vanden Abeele against
Belgium on 30 April 1905. De Neve made the opening goal of the match after 80 minutes. An
own goal by Dutchman
Ben Stom in the 86th minute was the equalizer, and the score was 1–1 after regular time. The Netherlands had won its first match ever, and De Neve had scored all four Dutch goals. He was also in the Dutch squad for a return match in
Rotterdam two weeks later, on 14 May 1905. The Netherlands won the match 4–0, with De Neve having scored two goals. De Neve played the third and final international match of his career on 13 May 1906, again against Belgium, this time resulting in a 2–3 loss. De Neve had scored six goals in three caps. He would remain the top scorer of the Netherlands national team until 21 March 1909, when
Edu Snethlage of De Neve's former club Quick scored the opening goal of a match against Belgium, his seventh goal for the Netherlands national team. A knee injury and military service in the Dutch East Indies forced De Neve to end his career as a football player in 1907. He published his memoirs, entitled
Koning Voetbal ("King Football"), in 1938, on the occasion of the Dutch East Indies taking part in the
1938 FIFA World Cup. ==Military career==