Early career Alexandrovskaya started learning to skate in 2004 when she was four. After competing as a single skater through 2011–2012, she began appearing in pairs with Vladislav Lysoy during the 2012–2013 season. She skated with Aleksandr Epifanov in 2014–2015 and 2015–2016.
Teaming with Windsor Responding to a query from Australian-based coaches Andrei and Galina Pachin, her coach
Nina Mozer suggested a tryout between Alexandrovskaya and
Harley Windsor in Moscow. The two began skating together in December 2015. Observing the tryout, the coaches believed that the skaters would make a good match due to similar technique and body types. Alexandrovskaya was released by Russia after a request from the Australian skating association, with help from Mozer.
2016–2017 season During the season, Alexandrovskaya/Windsor were coached by the Pachins in
Sydney and by Andrei Hekalo and Nina Mozer in Moscow. Their international debut came in early September 2016 at the
Junior Grand Prix (JGP) in
Ostrava,
Czech Republic. Ranked 6th in the short program and 9th in the free skate, the pair finished 8th overall. Later that month, the two competed at a JGP event in
Tallinn,
Estonia. They were awarded the gold medal ahead of three Russian pairs after placing third in the short and first in the free. They finished as the first substitutes for the JGP Final in
Marseille, France. Alexandrovskaya/Windsor made their senior debut in October 2016 at a
Challenger Series event, the
Finlandia Trophy; they placed sixth and obtained the minimum technical scores to compete at senior-level
ISU Championships. In December, the pair placed 5th in France at the
JGP Final, to which they were called up as replacements for Russia's
Ekaterina Borisova /
Dmitry Sopot. Windsor tore his
patella tendon in January 2017. The following month, the pair placed 11th at the
2017 Four Continents Championships in
Gangneung, South Korea. In March the same year, Alexandrovskaya/Windsor competed at the
2017 World Junior Championships in
Taipei, Taiwan. Ranked third in the short program and second in the free skate, they finished first overall, outscoring the silver medallists,
Aleksandra Boikova /
Dmitrii Kozlovskii of Russia, by 2.05 points. They became the first skaters representing Australia to win gold at one of the
ISU Figure Skating Championships and the first to finish on a podium at Junior Worlds since
1976, when
Elizabeth Cain /
Peter Cain took the pairs' bronze medal. A couple of weeks later, the pair competed at the senior-level
World Championships, which took place in
Helsinki, Finland. They qualified to the free skate and went on to finish 16th.
2017–2018 season In early September, Alexandrovskaya/Windsor finished fourth at the
2017 JGP in
Riga, Latvia. Later in the month, they competed at the
2017 CS Nebelhorn Trophy, the final
qualifying opportunity for the 2018 Winter Olympics. Ranked fourth in the short program and third in the free skate, they won their first senior international medal, bronze. Their result also allowed them to become the first Australian pair skaters to compete at the Olympics since
Danielle Carr /
Stephen Carr's appearance at the
1998 Winter Olympics. In October, Alexandrovskaya/Windsor placed first in both segments at the JGP event in
Gdańsk, Poland; they were awarded the gold medal and qualified for the
JGP Final in
Nagoya, Japan. In December, they won gold at the final, becoming the first Australian champions in the event's history. In January, Alexandrovskaya/Windsor finished 6th overall at the
2018 Four Continents Championships in
Taipei, Taiwan. They were awarded a small silver medal for their performance in the short program. In February, the two represented Australia at the
2018 Winter Olympics in
Pyeongchang, South Korea. Ranked 18th in the short program, they were not among the 16 pairs who advanced to the free skate. They were more successful at the
2018 World Championships in
Milan, Italy, placing 15th in the short program and 16th overall.
2018–2019 season Alexandrovskaya/Windsor moved to
Montreal to train with coaches Richard Gauthier and
Bruno Marcotte. Despite beginning the season with a bronze medal at the
2018 CS U.S. Classic, the move was overall not a success, and both struggled with health and fitness concerns. They finished sixth at the
2018 CS Nebelhorn Trophy, and then made their senior
Grand Prix debut, finishing seventh of eight teams at both
2018 Skate Canada International and
2018 Rostelecom Cup. Windsor developed a chronic foot inflammation that compelled them to miss both the
Four Continents and
World Championships.
2019–2020 season After their unsuccessful season, Alexandrovskaya/Windsor moved back to Sydney, and were joined there by former coach Andrei Khekalo. After months of experimentation, a solution was found for Windsor's foot inflammation that allowed them to resume training on ice. Alexandrovskaya/Windsor placed ninth at the
2019 CS Nebelhorn Trophy, and then finished seventh at the
2019 Skate America, their lone
Grand Prix assignment. They withdrew from the
2019 CS Warsaw Cup, and did not compete at
2019 Australian Figure Skating Championships, though they were still named to the
2020 Four Continents Figure Skating Championships team. They withdrew from that competition also, and Windsor announced that they had split due to Alexandrovskaya retiring because of health issues. It was subsequently reported by coach Khekalo that Alexandrovskaya had an
epileptic seizure in early January that prompted her retirement. == Death ==