The electric displacement field "
D" is defined as\mathbf{D} \equiv \varepsilon_{0} \mathbf{E} + \mathbf{P},where \varepsilon_{0} is the
vacuum permittivity (also called permittivity of free space),
E is the
electric field, and
P is the (macroscopic) density of the permanent and induced electric dipole moments in the material, called the
polarization density. The displacement field satisfies
Gauss's law in a dielectric: \nabla\cdot\mathbf{D} = \rho -\rho_\text{b} = \rho_\text{f} In this equation, \rho_\text{f} is the number of free charges per unit volume. These charges are the ones that have made the volume non-neutral, and they are sometimes referred to as the
space charge. This equation says, in effect, that the flux lines of
D must begin and end on the free charges. In contrast \rho_\text{b}, which is called the bound charge, is an effective density of the charges that are part of a
dipole. In the example of an insulating dielectric between metal capacitor plates, the only free charges are on the metal plates and dielectric contains only dipoles. The net, unbalanced bound charge at the metal/dielectric interface balances the charge on the metal plate. If the dielectric is replaced by a doped semiconductor or an ionised gas, etc, then electrons move relative to the ions, and if the system is finite they both contribute to \rho_\text{f} at the edges.
D is not determined exclusively by the free charge. As
E has a curl of zero in electrostatic situations, it follows that \nabla \times \mathbf{D} = \nabla \times \mathbf{P} The effect of this equation can be seen in the case of an object with a "frozen in" polarization like a bar
electret, the electric analogue to a bar magnet. There is no free charge in such a material, but the inherent polarization gives rise to an electric field, demonstrating that the
D field is not determined entirely by the free charge. The electric field is determined by using the above relation along with other boundary conditions on the
polarization density to yield the bound charges, which will, in turn, yield the electric field. == History ==