Born on the Victorian goldfields at Durban Lead,
Ballarat, Victoria, James was the eldest child of Ebenezer James and Clara Elizabeth James (née Maisey). The family moved to
Port Melbourne where James assisted her father in his work as chaplain at the Mission to Seaman. James married her cousin, George Henry James on 25 May 1889 at her parents' home in Port Melbourne. He was a schoolteacher with the Victorian Department of Education. == War and welfare work ==