Injected fluid In the United States, hydraulic fracturing fluids include
proppants,
radionuclide tracers, and
other chemicals, many of which are toxic. An expansive study conducted by the Yale School of Public Health in 2016 found numerous chemicals involved in or released by hydraulic fracturing are carcinogenic. The European Union regulatory regime requires full disclosure of all additives. In the United Kingdom, only chemicals that are "non hazardous in their application" are licensed by the
Environment Agency.
Flowback Less than half of injected water is recovered as flowback or later production brine, and in many cases recovery is <30%. As the fracturing fluid flows back through the well, it consists of spent fluids and may contain dissolved constituents such as minerals and
brine waters. Benzene is a known carcinogen which affects the central nervous system in the short term and can affect the bone marrow, blood production, immune system, and urogenital systems with long term exposure.
Surface spills Surface spills related to the hydraulic fracturing occur mainly because of equipment failure or engineering
misjudgments. Volatile chemicals held in waste water evaporation ponds can evaporate into the atmosphere, or overflow. The runoff can also end up in groundwater systems.
Groundwater may become contaminated by trucks carrying hydraulic fracturing chemicals and wastewater if they are involved in accidents on the way to hydraulic fracturing sites or disposal destinations. Evaporation and open ponds are not permitted. Regulations call for all pollution pathways to be identified and mitigated. The use of chemical proof drilling pads to contain chemical spills is required. In the UK, total gas security is required, and venting of methane is only permitted in an emergency.
Methane In September 2014, a study from the US
Proceedings of the National Academy of Sciences released a report that indicated that
methane contamination can be correlated to distance from a well in wells that were known to leak. This however was not caused by the hydraulic fracturing process, but by poor cementation of casings. Groundwater methane contamination has adverse effect on water quality and in extreme cases may lead to potential
explosion. the latter cause may also release injected fluids to the aquifer. Abandoned gas and oil wells also provide conduits to the surface in areas like Pennsylvania, where these are common. A study by
Cabot Oil and Gas examined the Duke study using a larger sample size, found that methane concentrations were related to topography, with the highest readings found in low-lying areas, rather than related to distance from gas production areas. Using a more precise isotopic analysis, they showed that the methane found in the water wells came from both the formations where hydraulic fracturing occurred, and from the shallower formations. The
Colorado Oil & Gas Conservation Commission investigates complaints from water well owners, and has found some wells to contain
biogenic methane unrelated to oil and gas wells, but others that have
thermogenic methane due to oil and gas wells with leaking well casing. A review published in February 2012 found no direct evidence that hydraulic fracturing actual injection phase resulted in contamination of ground water, and suggests that reported problems occur due to leaks in its fluid or waste storage apparatus; the review says that methane in water wells in some areas probably comes from natural resources. Another 2013 review found that hydraulic fracturing technologies are not free from risk of contaminating groundwater, and described the controversy over whether the methane that has been detected in private groundwater wells near hydraulic fracturing sites has been caused by drilling or by natural processes. ==Radionuclides==