A
crystal can be described as a
lattice of atoms, which in turn leads to the
reciprocal lattice. With electrons, neutrons or x-rays there is diffraction by the atoms, and if there is an incident plane wave \exp(2 \pi i \mathbf{k_0}\cdot \mathbf{r}) with a
wavevector \mathbf{k_0}, there will be outgoing wavevectors \mathbf{k_1} and \mathbf{k_2} as shown in the diagram after the wave has been
diffracted by the atoms. The energy of the waves (electron, neutron or x-ray) depends upon the magnitude of the wavevector, so if there is no change in energy (
elastic scattering) these have the same magnitude, that is they must all lie on the Ewald sphere. In the Figure the red dot is the origin for the wavevectors, the black spots are reciprocal lattice points (vectors) and shown in blue are three wavevectors. For the wavevector \mathbf{k_1} the corresponding reciprocal lattice point \mathbf{g_1} lies on the Ewald sphere, which is the condition for
Bragg diffraction. For \mathbf{k_2} the corresponding reciprocal lattice point \mathbf{g_2} is off the Ewald sphere, so \mathbf{k_2} = \mathbf{k_0} + \mathbf{g_2} + \mathbf{s} where \mathbf{s} is called the excitation error. The amplitude and also intensity of diffraction into the wavevector \mathbf{k_2} depends upon the
Fourier transform of the shape of the sample, the excitation error \mathbf{s}, the
structure factor for the relevant reciprocal lattice vector, and also whether the scattering is weak or strong. For neutrons and x-rays the scattering is generally weak so there is mainly
Bragg diffraction, but it is much stronger for
electron diffraction. ==See also==