Florence Dolphyne was a founding member, with
Mary Esther Kropp Dakubu and others, of the Linguistic Circle of Accra in 1967, which evolved into the Linguistic Association of Ghana. She was also involved with the
West African Linguistics Society Florence Dolphyne has been the chairperson of the National Council for Women and Development in Ghana. She has also been one of the commissioners who sat on the National Reconciliation Commission (2002 to 2004) which looked into the effects of military rule on people in Ghana. She has also been first and second Vice President of the Bible Society of Ghana. She was also a member of the Methodist University College Council and has been a Conference Member of
Methodist Church, Ghana since 1999. Dolphyne has also held visiting scholar positions at various institutions including
University of Ibadan in
Nigeria,
Fourah Bay College in
Sierra Leone,
Michigan State University and
University of California, Los Angeles in the
United States. She is a
Fulbright Senior Scholar. She has been the Chairperson of the Ghana Education Service between 2002 and 2006. She has also been a board member of the Ghana Education Trust Fund and
VALCO Trust Fund. ==Honours==