The Stokes–Helmholtz reversion–reciprocity principle was stated in part by
Stokes (1849) of
Hermann Helmholtz's
Handbuch der physiologischen Optik of 1856 as cited by
Gustav Kirchhoff and by
Max Planck. As cited by Kirchhoff in 1860, the principle is translated as follows:A ray of light proceeding from point 1 arrives at point 2 after suffering any number of refractions, reflections, &c. At point 1 let any two perpendicular planes
a1,
b1 be taken in the direction of the ray; and let the vibrations of the ray be divided into two parts, one in each of these planes. Take similar planes
a2,
b2 in the ray at point 2; then the following proposition may be demonstrated. If when the quantity of light
i polarized in the plane
a1 proceeds from 1 in the direction of the given ray, that part
k thereof of light polarized in
a2 arrives at 2, then, conversely, if the quantity of light
i polarized in
a2 proceeds from 2, the same quantity of light
k polarized in
a1 [Kirchhoff's published text here corrected by Wikipedia editor to agree with Helmholtz's 1867 text] will arrive at 1. In his magisterial proof of the validity of
Kirchhoff's law of equality of radiative emissivity and absorptivity, Planck makes repeated and essential use of the Stokes–Helmholtz reciprocity principle.
Rayleigh stated the basic idea of reciprocity as a consequence of the linearity of propagation of small vibrations, light consisting of sinusoidal vibrations in a linear medium. generally making use of quantum mechanical
time-reversal symmetry. As these more mathematically complicated proofs may detract from the simplicity of the theorem, A.P Pogany and P. S. Turner have proven it in only a few steps using a
Born series. Assuming a light source at a point A and an observation point O, with various scattering points r_1, r_2, ... r between them, the
Schrödinger equation may be used to represent the resulting wave function in space: :(\bigtriangledown^2 + 4\pi K^2)\Psi(\mathbf{r,r_A})=-4\pi K^2V(\mathbf{r})\Psi(\mathbf{r,r_A})+\delta(\mathbf{r-r_A}) By applying a
Green's function, the above equation can be solved for the wave function in an integral (and thus iterative) form: :\Psi(\mathbf{r,r_A})=G(\mathbf{r,r_A})-4\pi^2\int G(\mathbf{r,r'})V(\mathbf{r'})\Psi(\mathbf{r',r_A})d\mathbf{r'} where :G(\mathbf{r,r'})=-\frac{\exp(2\pi iK|\mathbf{r-r'}|)}. Next, it is valid to assume the solution inside the scattering medium at point O may be approximated by a Born series, making use of the
Born approximation in scattering theory. In doing so, the series may be iterated through in the usual way to generate the following integral solution: : \Psi(\mathbf{r_O,r_A})=G(\mathbf{r_O,r_A})-4\pi^2\int G(\mathbf{r_O,r_1})V(\mathbf{r_1})G(\mathbf{r_1,r_A}) d\mathbf{r_1} : +(-4\pi^2)^2\int d\mathbf{r_1}\int G(\mathbf{r_O,r_1})G(\mathbf{r_1,r_2})V(\mathbf{r_1})V(\mathbf{r_2})G(\mathbf{r_2,r_A})d\mathbf{r_2} : + (-4\pi^2)^3\int d\mathbf{r_1}\int d\mathbf{r_2}\int G(\mathbf{r_O,r_1})G(\mathbf{r_1,r_2})G(\mathbf{r_2,r_3})V(\mathbf{r_1})V(\mathbf{r_2})V(\mathbf{r_3})G(\mathbf{r_3,r_A})d\mathbf{r_3} : + ... Noting again the form of the Green's function, it is apparent that switching \mathbf{r_A} and \mathbf{r_O} in the above form will not change the result; that is to say, \Psi(\mathbf{r_A,r_O})=\Psi(\mathbf{r_O,r_A}) , which is the mathematical statement of the reciprocity theorem: switching the light source A and observation point O does not alter the observed wave function. == Applications ==