Piovi's professional career began in 2013 with
Argentine Primera División side
Vélez Sarsfield. It took Piovi until March 2016 to make his bow for Argentinos, playing the full ninety minutes in a goalless draw with
Temperley. In June 2016, Piovi extended his contract with the club. However, on 29 January 2018, Piovi completed a move to
Racing Club. Eight months later, after featuring in five matches for Racing Club, he departed the club on loan in August after agreeing to join
Gimnasia y Esgrima. He featured in twenty-seven matches in all competitions for Gimnasia, whilst also scoring his first senior goal in a
Copa de la Superliga win over
Newell's Old Boys on 21 April 2019. On 23 December 2023, Piovi joined
Liga MX side
Cruz Azul. ==Personal life==