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Hartree

The hartree, also known as the Hartree energy, is the unit of energy in the atomic units system, named after the British physicist Douglas Hartree. Its CODATA recommended value is Eh = 4.3597447222060(48)×10−18 J‍ = 27.211386245981(30) eV. The name "hartree" was suggested for this unit of energy.

Other relationships
: E_\mathrm{h} = {\hbar^2 \over {m_\mathrm{e} a^2_0}} = m_\mathrm{e}\left(\frac{e^2}{4\pi\varepsilon_0\hbar}\right)^2 = m_\mathrm{e} c^2 \alpha^2 = {\hbar c \alpha \over {a_0}} :: = 2 Ry = 2 Rhc :: = :: = :: = :: ≘ :: ≘ :: ≘ :: ≘ where: • ħ is the reduced Planck constant, • me is the electron mass, • e is the elementary charge, • a0 is the Bohr radius, • ε0 is the electric constant, • c is the speed of light in vacuum, and • α is the fine-structure constant. Effective hartree units are used in semiconductor physics where e^2 is replaced by e^2/\varepsilon and \varepsilon is the static dielectric constant. Also, the electron mass is replaced by the effective band mass m^*. The effective hartree in semiconductors becomes small enough to be measured in millielectronvolts (meV). == See also ==
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