She was commissioned in 1694 under the command of Captain Edward Rigby, RN. In December 1694 she was under the command of Captain John Douglas, RN for service in the English Channel. On 1 October 1697 she was under command of Captain Hercules Mitchell followed in 1701 Captain Joseph Soanes, RN. Captain John Mitchell, RN was in command for the Battle of Vigo Bay on 12 October 1702.In 1703 Commander John Trotter, RN. At the Battle of Velez-Malaga on 13 August 1704 she was under the command of Commander Edmund Hicks, RN as part of the cester squadron. On 9 March 1705 Captain Michael Sansom, RN took command for service in the Mediterranean. In 1707, she belonged to
Admiral Sir Cloudesley Shovell's fleet. She saw action during the unsuccessful
Battle of Toulon and was present during the
great naval disaster off the Isles of Scilly when Shovell and four of his ships (, , and ) were lost, claiming the lives of nearly 2,000 sailors.
Phoenix ran ashore between
Tresco and
St Martin's and had to be beached, but could be kept seaworthy and finally managed to reach
Portsmouth. She was salved and laid up at Plymouth during 1708/09. On 12 March 1708 she was ordered to be rebuilt as a 24-gun sixth rate. ==Rebuild as a 24-gun Sixth Rate 1708/09 Plymouth==