Operators and state vectors in the interaction picture are related by a change of basis (
unitary transformation) to those same operators and state vectors in the Schrödinger picture. To switch into the interaction picture, we divide the Schrödinger picture
Hamiltonian into two parts: {{Equation box 1 Any possible choice of parts will yield a valid interaction picture; but in order for the interaction picture to be useful in simplifying the analysis of a problem, the parts will typically be chosen so that
H0,S is well understood and exactly solvable, while
H1,S contains some harder-to-analyze perturbation to this system. If the Hamiltonian has
explicit time-dependence (for example, if the quantum system interacts with an applied external electric field that varies in time), it will usually be advantageous to include the explicitly time-dependent terms with
H1,S, leaving
H0,S time-independent:{{Equation box 1
State vectors Let |\psi_\text{S}(t)\rangle = \mathrm{e}^{-\mathrm{i}H_\text{S}t/\hbar}|\psi(0)\rangle be the time-dependent state vector in the Schrödinger picture. A state vector in the interaction picture, |\psi_\text{I}(t)\rangle, is defined with an additional time-dependent unitary transformation. {{Equation box 1
Operators An operator in the interaction picture is defined as {{Equation box 1 Note that
AS(
t) will typically not depend on and can be rewritten as just
AS. It only depends on if the operator has "explicit time dependence", for example, due to its dependence on an applied external time-varying electric field. Another instance of explicit time dependence may occur when
AS(
t) is a density matrix (see below).
Hamiltonian operator For the operator H_0 itself, the interaction picture and Schrödinger picture coincide: :H_{0,\text{I}}(t) = \mathrm{e}^{\mathrm{i} H_{0,\text{S}} t / \hbar} H_{0,\text{S}} \mathrm{e}^{-\mathrm{i} H_{0,\text{S}} t / \hbar} = H_{0,\text{S}}. This is easily seen through the fact that operators
commute with differentiable functions of themselves. This particular operator then can be called H_0 without ambiguity. For the perturbation Hamiltonian H_{1,\text{I}}, however, :H_{1,\text{I}}(t) = \mathrm{e}^{\mathrm{i} H_{0,\text{S}} t / \hbar} H_{1,\text{S}} \mathrm{e}^{-\mathrm{i} H_{0,\text{S}} t / \hbar}, where the interaction-picture perturbation Hamiltonian becomes a time-dependent Hamiltonian, unless [
H1,S,
H0,S] = 0. It is possible to obtain the interaction picture for a time-dependent Hamiltonian
H0,S(
t) as well, but the exponentials need to be replaced by the unitary propagator for the evolution generated by
H0,S(
t), or more explicitly with a time-ordered exponential integral.
Density matrix The
density matrix can be shown to transform to the interaction picture in the same way as any other operator. In particular, let and be the density matrices in the interaction picture and the Schrödinger picture respectively. If there is probability to be in the physical state |
ψn⟩, then :\begin{align} \rho_\text{I}(t) &= \sum_n p_n(t) \left|\psi_{n,\text{I}}(t)\right\rang \left\lang \psi_{n,\text{I}}(t)\right| \\ &= \sum_n p_n(t) \mathrm{e}^{\mathrm{i} H_{0,\text{S}} t / \hbar} \left|\psi_{n,\text{S}}(t)\right\rang \left\lang \psi_{n,\text{S}}(t)\right| \mathrm{e}^{-\mathrm{i} H_{0,\text{S}} t / \hbar} \\ &= \mathrm{e}^{\mathrm{i} H_{0,\text{S}} t / \hbar} \rho_\text{S}(t) \mathrm{e}^{-\mathrm{i} H_{0,\text{S}} t / \hbar}. \end{align}
Time-evolution Time-evolution of states Transforming the
Schrödinger equation into the interaction picture gives : \mathrm{i} \hbar \frac{\mathrm{d}}{\mathrm{d}t} |\psi_\text{I}(t)\rang = H_{1,\text{I}}(t) |\psi_\text{I}(t)\rang, which states that in the interaction picture, a quantum state is evolved by the interaction part of the Hamiltonian as expressed in the interaction picture. A proof is given in Fetter and Walecka.
Time-evolution of operators If the operator
AS is time-independent (i.e., does not have "explicit time dependence"; see above), then the corresponding time evolution for
AI(
t) is given by : \mathrm{i}\hbar\frac{\mathrm{d}}{\mathrm{d}t}A_\text{I}(t) = [A_\text{I}(t),H_{0,\text{S}}]. In the interaction picture the operators evolve in time like the operators in the
Heisenberg picture with the Hamiltonian .
Time-evolution of the density matrix The evolution of the
density matrix in the interaction picture is : \mathrm{i}\hbar \frac{\mathrm{d}}{\mathrm{d}t} \rho_\text{I}(t) = [H_{1,\text{I}}(t), \rho_\text{I}(t)], in consistency with the Schrödinger equation in the interaction picture. ==Expectation values==