During Goulart's first ever fashion show appearance, she experienced a
wardrobe malfunction when her top fell open. The incident made many Brazilian newspapers. She eventually put this event behind her and returned to the runway to model collections for A-list designers such as
Alberta Ferretti,
Bill Blass,
Balenciaga,
Bottega Veneta,
Isabel Marant,
Givenchy,
Altuzarra,
Oscar de la Renta,
Valentino,
Balmain,
Jil Sander,
Chanel,
Michael Kors,
Ralph Lauren,
Emilio Pucci,
Dolce and Gabbana,
Emanuel Ungaro,
Loewe,
Roberto Cavalli and
Stella McCartney, among others. Goulart has also modeled for
H&M,
Express,
Neiman Marcus,
Missoni and
DSquared². In 2005, Goulart appeared on the covers of the April edition of
Marie Claire France and, in December,
Vogue Brazil. She first appeared in the
Victoria's Secret Fashion Show in 2005, the year she was contracted as an Angel. She received a star on the Hollywood "Walk of Fame" prior to the
Victoria's Secret Fashion Show 2007. Although she is no longer an Angel, Goulart walked in every Victoria's Secret Fashion Show from 2005 to 2016. In 2008, she replaced fellow Victoria's Secret Angel
Alessandra Ambrosio as the face of A/X Armani Exchange and she was featured in three seasonal print campaigns for the label. In 2010, Goulart appeared on the cover of the October issue for
GQ Mexico,
Vogue Brasil and appeared in a campaign for
Avon. In the same year, she was voted the best international top model by the magazine
Glamour Mexico. In 2011, Goulart appeared in the
Sports Illustrated Swimsuit Issue. She can be seen in the spring/summer 2011 campaign for Dolce and Gabbana, the Pre-Fall 2011 campaign for Givenchy, Yamamay's 10th Anniversary Collection and the Fall/Winter 2011 campaign for DKNY Jeans. The same year, she ranked number 100 in
FHM magazine's list of the 100 Sexiest Women In The World. She also appeared on one of the four covers of Elle Brasil. In February 2012, she was photographed by Dusan Reljin for
Vogue Spain, and later that year by
Mario Testino, again for
Vogue Spain, in an editorial entitled "Las majas", which also featured
Alessandra Ambrosio,
Doutzen Kroes,
Miranda Kerr and
Isabeli Fontana. In November, she was recognised as "Fashion Personality of the Year" by the Brazilian magazine
Isto é Gente, and she also appeared on the cover of
Glamour Brazil in December 2012. In February 2013 she appeared on the cover of one of the four issues of
Vogue Brasil, together with
Bette Franke,
Magdalena Frackowiak, and
Mirte Maas. In mid-2013, she became the face of
MAC Cosmetics Tropical Taboo range and she was photographed by Zee Nunes for the October edition of
Vogue Brazil in an editorial entitled "Olympiada Fashion". Later that year she appeared in a campaign for Agua De Coco promoting its spring/summer 2014 beachwear collection. She also appeared on the cover of
GQ Portugal in December 2013, after she was elected as the magazine's "International Woman of the Year" in May of that year. ==Public image==