Early work Thomson's prize-winning master's work,
Treatise on the motion of vortex rings, shows his early interest in atomic structure. In it, Thomson mathematically described the motions of
Lord Kelvin's
vortex theory of the atom. was a readable introduction to a wide variety of subjects, and achieved considerable popularity as a textbook. He estimated the mass of cathode rays by measuring the heat generated when the rays hit a thermal junction and comparing this with the magnetic deflection of the rays. His experiments suggested not only that cathode rays were over 1,000 times lighter than the hydrogen atom, but also that their mass was the same in whichever type of atom they came from. He concluded that the rays were composed of very light, negatively charged particles which were a universal building block of atoms. He called the particles "corpuscles", but later scientists preferred the name
electron, which had been suggested by
George Johnstone Stoney in 1891, prior to Thomson's discovery. In April 1897, Thomson had only early indications that the cathode rays could be deflected electrically (previous investigators such as
Heinrich Hertz had thought they could not be). A month after Thomson's announcement of the corpuscle, he found that he could reliably deflect the rays by an electric field if he evacuated the discharge tube to a very low pressure. By comparing the deflection of a beam of cathode rays by electric and magnetic fields he obtained more robust measurements of the mass-to-charge ratio that confirmed his previous estimates. This became the classic means of measuring the charge-to-mass ratio of the electron. Later in 1899 he measured the charge of the electron to be of . Thomson believed that the corpuscles emerged from the atoms of the trace gas inside his
cathode-ray tubes. He thus concluded that atoms were divisible, and that the corpuscles were their building blocks. In 1904, Thomson suggested a model of the atom, hypothesizing that it was a sphere of positive matter within which electrostatic forces determined the positioning of the corpuscles. Thomson made the discovery around the same time that
Walter Kaufmann and
Emil Wiechert discovered the correct mass to charge ratio of these cathode rays (electrons). The name
electron was adopted for these particles by the scientific community, mainly due to the advocation by
George Francis FitzGerald,
Joseph Larmor, and
Hendrik Lorentz. The term was originally coined by
George Johnstone Stoney in 1891 as a tentative name for the basic unit of electrical charge (which had then yet to be discovered). For some years Thomson resisted using the word "electron" because he didn't like how some physicists talked of a "positive electron" that was supposed to be the elementary unit of positive charge just as the "negative electron" is the elementary unit of negative charge. Thomson preferred to stick with the word "corpuscle" which he strictly defined as negatively charged. He relented by 1914, using the word "electron" in his book
The Atomic Theory. In 1920, Rutherford and his fellows agreed to call the nucleus of the hydrogen ion "proton", establishing a distinct name for the smallest known positively-charged particle of matter (that can exist independently anyway).
Isotopes and mass spectrometry In 1912, as part of his exploration into the composition of the streams of positively charged particles then known as
canal rays, Thomson and his research assistant,
F. W. Aston, channelled a stream of neon ions through a magnetic and an electric field and measured its deflection by placing a photographic plate in its path. This was the first evidence for isotopes of a stable element;
Frederick Soddy had previously proposed the existence of isotopes to explain the decay of certain
radioactive elements. Thomson's separation of neon isotopes by their mass was the first example of
mass spectrometry, which was subsequently improved and developed into a general method by
F. W. Aston and by
A. J. Dempster.
Experiments with cathode rays Earlier, physicists debated whether cathode rays were immaterial like light ("some process in the
aether") or were "in fact wholly material, and ... mark the paths of particles of matter charged with negative electricity", quoting Thomson.
Electrical charge While supporters of the aetherial theory accepted the possibility that negatively charged particles are produced in
Crookes tubes, they believed that they are a mere by-product and that the cathode rays themselves are immaterial. Thomson set out to investigate whether or not he could actually separate the charge from the rays. Thomson constructed a Crookes tube with an
electrometer set to one side, out of the direct path of the cathode rays. Thomson could trace the path of the ray by observing the phosphorescent patch it created where it hit the surface of the tube. Thomson observed that the electrometer registered a charge only when he deflected the cathode ray to it with a magnet. He concluded that the negative charge and the rays were one and the same. In 1906, Thomson demonstrated that
hydrogen had only a single
electron per atom. Previous theories allowed various numbers of electrons. From 1916 to 1918, Thomson chaired the "Committee appointed by the Prime Minister to enquire into the Position of Natural Science in the Educational System of Great Britain". The Report of the Committee, published in 1918, was known as the Thomson Report. == Family ==