Popolo is active in philanthropy and education. He joined the
Boston College Board of Trustees in June 2023, having previously served on the university’s Board of Regents. He and his wife have supported a range of initiatives at Boston College, including scholarships and endowments. Their contributions include the establishment of the Popolo Family Executive Directorship at the Edmund H. Shea Jr. Center for Entrepreneurship, as well as the Popolo Family Running Back Football Scholarship, and endowed the Edward Connelly Offensive Coordinator position in 2025 in honor of his maternal grandfather. Popolo and his wife, Chris, serve on the executive committee of Soaring Higher, Boston College’s $3 billion fundraising campaign. He also serves on the executive board of the Cox School of Business at
Southern Methodist University. In addition, he co-founded and is a director of the HALO Initiative for Catholic Education in Dallas. In 2022, Popolo co-founded
Friends of the Heights, the official
Name, Image, and Likeness (NIL) collective for student-athletes at Boston College. Popolo has expressed a strong interest in improving education outcomes, assisting those in need, and supporting charitable organizations that reflect his faith. He believes that entrepreneurs play a key role in driving progress across various fields. Beyond his business and diplomatic pursuits, Popolo expressed a desire to eventually pursue
philanthropy full-time. He and his wife believe they are "called to serve" and are passionate about improving education outcomes, helping people get back on their feet, and supporting organizations aligned with their respective faiths. == Political activities ==