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Lead telluride

Lead telluride is a compound of lead and tellurium (PbTe). It crystallizes in the NaCl crystal structure with Pb atoms occupying the cation and Te forming the anionic lattice. It is a narrow gap semiconductor with a band gap of 0.32 eV. It occurs naturally as the mineral altaite.

Properties
Dielectric constant ~1000. • Electron Effective mass ~ 0.01me • Hole mobility, μp = 600 cm2 V−1 s−1 (0 K); 4000 cm2 V−1 s−1 (300 K) • Seebeck coefficient: ~326 μV/K (undoped, at 300K), ~200 μV/K (Ag-doped) == Applications ==
Applications
PbTe has proven to be a very important intermediate thermoelectric material. The performance of thermoelectric materials can be evaluated by the figure of merit, ZT=S^2\sigma T/\kappa, in which S is the Seebeck coefficient, \sigma is the electrical conductivity and \kappa is the thermal conductivity. In order to improve the thermoelectric performance of materials, the power factor (S^2\sigma) needs to be maximized and the thermal conductivity needs to be minimized. With this approach, point defects, nanoscale precipitates and mesoscale grain boundaries are introduced as effective scattering centers for phonons with different mean free paths, without affecting charge carrier transport. By applying this method, the record value for zT of PbTe that has been achieved in Na doped PbTe-SrTe system is approximately 2.2. In addition, PbTe is also often alloyed with tin to make lead tin telluride, which is used as an infrared detector material. == See also ==
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