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Leuckart thiophenol reaction

The Leuckart thiophenol reaction is the decomposition of a diazoxanthate, by gentle warming in a slightly acidic cuprous medium, to its corresponding aryl xanthates which give aryl thiols on alkaline hydrolysis and aryl thioethers on further warming.

Key Points
The reaction provides a route to introduce Sulfur into aromatic rings. Products: Aryl Thiols and Aryl Thioethers. Cu(I) acts as a catalyst to facilitate the decomposition of the diazo intermediate. ==Applications==
Applications
Preparation of Aryl Thiols (Ar–SH): Important in Pharmaceuticals, Dyes, and Agrochemicals. Synthesis of Aryl Thioethers (Ar–S–Ar): Used in Polymers, Drugs, Materials Chemistry. Substitution of Diazonium salts with Sulfur groups, expanding the Sandmeyer-resembling transformations. ==References==
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