Single-ply membranes – There are three types of single-ply, or elastoplastic, products in use today that are defined by the chemical properties they possess: cured (or vulcanized) elastomers, uncured elastomers, and plastomers. '
Cured elastomers (often referred to as thermoset)''''' – Thermosets are synthetic rubbers that have undergone the
vulcanization or "curing" process. Seams of materials are bonded by adhesives or chemicals, which over time weaken and separate unless maintained or reinforced. The finished roof's thickness is usually between 30 and 120 mils (thousandths of an inch; 0.75 mm to 1.50 mm). The most commonly used cured
elastomer membranes are ethylene propylene diene monomer (commonly
EPDM) and
neoprene, although all thermoset products combined fail to account for more than 10% of all commercial roofing. This is in part due to studies being released in the 1980s to early 2000s showing the average lifespan of thermoset membranes between 15 and 20 years, although the products have undergone massive alterations since then.
Uncured elastomers (sometimes grouped with thermosets for simplicity) – Uncured elastomers are installed in a manner similar to thermoplastics in that they can be heat or solvent welded. The material then cures over time once exposed to the elements, and then exhibits the same qualities as vulcanized elastomers. The most commonly used uncured elastomers are chlorosulfonated polyethylene (CSPE),
chlorinated polyethylene (CPE), polyisobutylene (PIB), nitrile butadiene polymer (NBP), although none of the products are known to be commonly used in the last decade, in part due to environmental concerns brought up regarding the chemical curing processes in the late 1990s. Thermosets are often referenced for their easy installation methods, high chemical resistances, having higher impact resistances (for some membranes), and resistance to high temperatures. '
Plastomers (often referred to as thermoplastics
)' – Thermoplastics are membranes that are heat welded and develop strength in the welds at least equal to the original membrane material, forming a much stronger bond than chemically bonded thermosets. The most commonly used thermoplastics are PVC, KEE and TPO, taking up over 55% of the commercial roofing market. However, a common misconception is that these are the only types of materials.
Modified bitumen – Polymer modified bitumen membranes were developed in Europe in the mid-1960s and have been in common use throughout the United States since 1975. they are composed of one or more premanufactured sheets consisting of asphalt, reinforcing layers, and in some cases a surfacing is applied. During manufacture, plastics or rubbers are added to the bitumen while heating, modifying its properties to give it a higher softening point and greater elasticity. There are several ways of connecting pieces of this material. The most common method for bonding seams is by torch-application; however, the options of hot-mopping, using cold
adhesive, and self-adhering materials are still sometimes used.
Copolymers commonly used to modify asphalt include
atactic polypropylene (APP), styrene-butadiene-styrene (SBS),
styrene-butadiene rubber (SBR), and styrene-ethylene-butylene-styrene (SEBS). ==Advantages over asphalt flat roofing systems==