The mining history of the Rammelsberg occurred as a continuous process in different phases. Initially the main product was copper ore, then, (much) later lead, and with lead, silver. The analysis of written sources and archaeological finds of unsmelted pieces of ore and slag found during archaeological excavations between 1981 and 1985 at Düna (near
Osterode) in the South Harz indicates that the earliest mining activity at the Rammelsberg occurred in the late 7th century AD.
Anglo-Saxon burial objects made of Harz ore were also excavated in England.
Middle Ages Mining on the Rammelsberg was first mentioned in the records around 968 by the
Saxon chronicler,
Widukind of Corvey. According to his
Res gestae saxonicae, Emperor Otto the Great had
silver ore deposits () opened and extracted. The mining settlement of Goslar was not mentioned until 979. In 1005, attracted by the presence of silver, King
Henry II of Germany had the
Imperial Palace of Goslar (
Kaiserpfalz Goslar) built at the foot of Mt. Rammelsberg, and held his first Imperial Assembly there in 1009. Extended by his
Salian successors
Conrad II and
Henry III, the palace of Goslar gradually replaced the former
Royal palace of Werla. The profitable mines remained a
Reichsgut directly belonging to the
Holy Roman Emperor. When in 1175 Emperor
Frederick Barbarossa called for support on his campaign against the Italian cities of the
Lombard League, the
Welf duke
Henry the Lion demanded his enfeoffment with the Goslar mines in return, which Frederick denied. Duke Henry laid siege to the town and had the mining installations demolished. Restored after his deposition in 1180, the Rammelberg mines were again contested in 1198/99 during the Welf-
Hohenstaufen throne quarrel between his son
Otto IV and Frederick's son
Philip of Swabia. After Imperial influence waned, the mines were held in pledge by the council of the
Imperial city of Goslar, who officially purchased the entitlement to the rights and royalties from mining (
Bergregal) in 1359. A
mining accident is documented in 1376, when more than 100 miners were buried and killed. The main ores mined at Rammelsberg were lead-zinc ore, copper ore, sulphur ore, mixed ore (
Melierterz), brown spar (
Braunerz), barite ore (
Grauerz), banding ore (
Banderz) and kniest along with the important minerals of
galena,
chalcopyrite,
sphalerite,
baryte and
vitriols. The chief metals extracted from these ores included silver, lead, copper and zinc, on which the wealth of Goslar was based. Because of this wealth, Goslar and the Rammelsberg mines were influential in the
Hanseatic League throughout the 1440s, but in 1552, control over the mine was transferred from Goslar to the
Margraviate of Brandenburg In autumn 2009 several
exploratory bores were sunk in the area of the Hessenkopf and Gosetal to a depth of 500–600 metres. At the end of January 2010, after a news blackout of several months, the company announced that they would soon be drilling to a
depth of 800 metres, where they suspected there would be rich mineral deposits. == World Heritage Site ==