Critical reception MTV Unplugged – Live in Athens received mostly positive reviews from the music press. Gregory Heany of
AllMusic stated that the set feels "quite personal" despite being recorded in a large venue, as the songs reveal emotions and, in the case of the power ballads, a "new level of simplicity". He concluded his review by saying: "With two discs of acoustic goodness, Scorpions fans will definitely want to give this a listen." Kevin Wierzbicki of AntiMusic gave it a rating of five out of five stars, highlighting the band's "flexibility" in adding new elements to the songs, the guest vocalists, Schenker and Jabs' skill on acoustic guitar, Meine's "patented" voice, and the "playful rhythm" of Kottak and
Paweł Mąciwoda. He added, "Scorpions have released many live efforts but none until now have been free of bombast" because "there is much more here than you'd get if the same set had been played through a stack of
Marshalls." Mark Uricheck of the American magazine
Elmore Magazine noted that the album's strength lies in the "custom-tailored modifications" of the songs and it is a "sensuous achievement in terms of arrangement". He also distinguished the duet between Meine and Harket on "Wind of Change", as well as that of Meine with Cäthe on "In Trance", as the latter "roars with a somber, orchestral intensity". In turn, he highlighted Gardemar's performance and the folk accents on "When the Smoke Is Going Down", the ballad "Love is the Answer", and "Rock You Like a Hurricane", as it "resonates with a
Wagnerian air of classical inspiration". Chris McHugh of the American
Pittsburgh Music Magazine wrote that the arrangements are "dynamic and robust" and every visual and auditory detail makes the show worth watching. He also reviewed that the sound is full and rich, the quality is exceptional, and the music is perfect, as they "stay true to the spirit and energy of Scorpions". Overall, he reflected that "it's an entertaining set, although a bit more laid back and calm compared to the band's earlier catalog", but it is "a must-have for any die-hard Scorpions fan". Canadian critic
Martin Popoff declared it an "elaborate and interesting acoustic recording", where the band "sets up various arrangements that lighten the tempo of many of their hits". About the show itself, he added that it is "captured with much splendor". 's vocal quality was one of the aspects most praised by critics.|230px Alexander Kolbe of the German magazine
Rocks commented that the execution is "exciting", even more so than on 2001's
Acoustica. He highlighted the "variable instrumentation and the modified arrangements" that, in certain songs, venture into
worldbeat, such as the Cajun-Greek folk blend on "Sting in the Tail", the
Indian ambiance on "When You Came Into My Life", or the Far Eastern touch on "Passion Rules the Game". He also opined that Meine's performance "is magnificent again", although he noted that "Love is the Answer" is a "bad moment", mainly due to Schenker's vocal intonation. Matt Wardlaw of
Ultimate Classic Rock stated there is a variety of instrumentation that makes the reworked material feel "intimate", but according to the author, the most interesting thing is that the band delves into their song catalog to present "unexpected surprises". In summary, Wardlaw commented that they "deliver a performance that has a pretty satisfying touch." On the other hand, thanks to this production, the band received two nominations at the German
Echo Awards in the categories of Best National Rock/Alternative Group and Best Music DVD. It ended 2013 as the seventy-fourth best-selling album of the year. On the German chart compiled by
Billboard, it also reached number five, but only stayed for three weeks. In the same year, the
Bundesverband Musikindustrie (BVMI) certified the audio version gold, for selling over 100,000 copies. In 2016, the DVD also achieved gold certification for surpassing 25,000 units. In Greece, it reached number 8 on
Billboard Greece Albums for the week of 17 May 2014. In other European countries,
MTV Unplugged – Live in Athens reached position 29 on the
Swiss Hitparade, 50 on the Spanish
Top 100 Álbumes, 90 on the
Ultratop chart in
Wallonia, Belgium, and 195 in
Flanders, Belgium. In France, it reached number 85 on the
French Albums Chart. As of 2018, the French company InfoDisc estimated its sales at 14,100 units, without considering
streaming. In South Korea, it placed at number 61 on the
Circle Chart. On 8 February 2014, it entered the US
Billboard 200 at number 113 and stayed for only one week. On that date, it reached the same position on the Top Album Sales chart. On other
Billboard charts, it reached number 7 on Top Hard Rock Albums, number 27 on
Independent Albums, number 41 on both Top Rock Albums and Top Rock & Alternative Albums, and number 106 on Top Current Album Sales. ;DVD Regarding the audiovisual release, for the week of 15 December 2013 it reached number 9 on the Swiss Musik DVD Charts Top 10. In Spain, on 2 December 2013 it debuted at number fifteen on the Top 20 DVD Musical, and in 2014 it re-entered on two occasions: on 5 May at number 17 and on 6 June at number 20. By 16 June, it had reached number thirteen as its peak position. In the United Kingdom, it held the number 41 spot on the
UK Music Video Chart for 14 December 2013, while in Sweden it placed at number 16. In France, it ended 2013 as the thirty-third best-selling DVD with 3,600 copies, while the following year it finished in seventy-first place with 2,100 units. == Track listing ==