Natalya Petrovna had five children with her husband. Her first son, Pyotr, was born in 1767, but died in 1778. Her second son
Boris, born in 1769, became a lieutenant general, before dying in 1813 of wounds he sustained at the
Battle of Borodino.
Dmitry was born in 1771 and rose to be a statesman and military writer. He married
Tatiana Vasilyevna Vasilchikova, with whom he had five children, before his death in 1844. The Golitsyn's two daughters,
Ekaterina (1770–1854) and
Sofia (1775–1845), married
Stepan Stepanovich Apraksin and
Pavel Alexandrovich Stroganov respectively, with each having five children. All received excellent educations, and while living in Paris before the revolution it was noted that they spoke French better than they did Russian. Princess Golitsyna acquired a reputation as the autocrat of her family, being both capricious and domineering. Her children were afraid to sit in her presence; when her son
Boris Vladimirovich did something to offend her, she refused to speak to him for over a year. Boris died during the
Napoleonic Wars, leaving behind two orphaned illegitimate children he had had with a gypsy woman. In fear of Natalya's reaction to this news, their existence was kept a secret from her, and they were quietly raised with the family of Boris's brother
Dmitry. On the death of her husband in 1798, Natalya's sons became heirs to the family fortune, but did not dare to demand their rightful share of the inheritance from their mother. On their marriages Princess Golitsyna's daughters received 2,000 serfs, while her sons received an annuity of 50,000 rubles. When Dmitry was appointed
Governor-General of Moscow in 1820, a social position that required him to give receptions and balls, and to be engaged in charity, he soon fell into debt, as the allowance he received from his mother was not enough to support such a life. Eventually
Emperor Nicholas I had to ask Princess Golitsyna to increase her son's allowance so that he would not compromise his name and position with debts. The princess added another 50,000 rubles, considering this a generous sum. It was only on his mother's death, seven years before his own, that Prince Dmitry received his full inheritance, amounting to 16,000 serfs. ==Later life==