Niobium pentoxide

It has many polymorphic forms all based largely on octahedrally coordinated niobium atoms. The polymorphs are identified with a variety of prefixes. There is an uncharacterised solid hydrate, , the so-called niobic acid (previously called columbic acid), which can be prepared by hydrolysis of a basic solution of niobium pentachloride or Nb2O5 dissolved in HF. Molten niobium pentoxide has lower mean coordination numbers than the crystalline forms, with a structure comprising mostly NbO5 and NbO6 polyhedra. ==Production==

Hydrolysis Nb2O5 is prepared by hydrolysis of alkali-metal niobates, alkoxides or fluoride using base. Such ostensibly simple procedures afford hydrated oxides that can then be calcined. Pure Nb2O5 can also be prepared by hydrolysis of NbCl5: :2 NbCl5 + 5 H2O → Nb2O5 + 10 HCl A method of production via sol-gel techniques has been reported hydrolysing niobium alkoxides in the presence of acetic acid, followed by calcination of the gels to produce the orthorhombic form, Oxidation Given that Nb2O5 is the most common and robust compound of niobium, many methods, both practical and esoteric, exist for its formation. The oxide for example, arises when niobium metal is oxidised in air. ==Reactions==

Nb2O5 is attacked by HF and dissolves in fused alkali. Reduction to the metal The conversion of Nb2O5 is the main route for the industrial production of niobium metal. In the 1980s, about 15,000,000 kg of Nb2O5 were consumed annually for reduction to the metal. The main method is reduction of this oxide with aluminium: :3 Nb2O5 + 10 Al → 6 Nb + 5 Al2O3 An alternative but less practiced route involves carbothermal reduction, which proceeds via reduction with carbon and forms the basis of the two stage Balke process: :Nb2O5 + 7 C → 2 NbC + 5 CO (heated under vacuum at 1800 °C) :5 NbC + Nb2O5 → 7 Nb + 5 CO Conversion to halides Many methods are known for conversion of Nb2O5 to the halides. The main problem is incomplete reaction to give the oxyhalides. In the laboratory, the conversion can be effected with thionyl chloride: :Nb2O5 + 5 SOCl2 → 2 NbCl5 + 5 SO2 Nb2O5 reacts with CCl4 to give niobium oxychloride NbOCl3. Conversion to niobates Treating Nb2O5 with aqueous NaOH at 200 °C can give crystalline sodium niobate, NaNbO3 whereas the reaction with KOH may yield soluble Lindqvist-type hexaniobates, . Lithium niobates such as LiNbO3 and Li3NbO4 can be prepared by reaction lithium carbonate and Nb2O5. :Nb2O5 + 3Nb → 5 NbO The burgundy-coloured niobium(III) oxide, one of the first superconducting oxides, can be prepared again by an comproportionation: :Li3NbO4 + 2 NbO → 3 LiNbO2 ==Uses==

Niobium pentoxide is used mainly in the production of niobium metal, ==External links==