The most important mechanism affecting NMR relaxation is grain-surface relaxation. Molecules in fluids are in constant
Brownian motion, diffusing about the pore space and bouncing off the grain surfaces. Upon interaction with the grain surface, hydrogen protons can transfer some nuclear spin energy to the grain (contributing to
T1 relaxation) or irreversibley dephase (contributing to
T2 relaxation). Therefore the speed of relaxation most significantly depends on how often the hydrogen nuclei collide with the grain surface and this is controlled by the surface-to-volume ratio of the pore in which the nuclei are located. Collisions are less frequent in larger pores, resulting in a slower decay of the NMR signal amplitude and allowing a petrophysicist to understand the distribution of pore sizes. ==See also==