Materials Glass optical fibers are almost always made from
silica, but some other materials, such as
fluorozirconate,
fluoroaluminate, and
chalcogenide glasses as well as crystalline materials like
sapphire, are used for longer-wavelength infrared or other specialized applications. Silica and fluoride glasses usually have refractive indices of about 1.5, but some materials such as the
chalcogenides can have indices as high as 3. Typically the index difference between core and cladding is less than one percent.
Plastic optical fibers (POF) are commonly step-index multi-mode fibers with a core diameter of 0.5 millimeters or larger. POF typically have higher attenuation coefficients than glass fibers, 1 dB/m or higher, and this high attenuation limits the range of POF-based systems.
Silica Silica exhibits fairly good optical transmission over a wide range of wavelengths. In the
near-infrared (near IR) portion of the spectrum, particularly around 1.5 μm, silica can have extremely low absorption and scattering losses of the order of . Such low losses depend on using ultra-pure silica. A high transparency in the 1.4-μm region is achieved by maintaining a low concentration of
hydroxyl groups (OH). Alternatively, a high OH
concentration is better for transmission in the
ultraviolet (UV) region. Silica can be drawn into fibers at reasonably high temperatures and has a fairly broad
glass transformation range. One other advantage is that fusion splicing and
cleaving of silica fibers is relatively effective. Silica fiber also has high mechanical strength against both pulling and even bending, provided that the fiber is not too thick and that the surfaces have been well prepared during processing. Even simple cleaving of the ends of the fiber can provide nicely flat surfaces with acceptable optical quality. Silica is also relatively
chemically inert. In particular, it is not
hygroscopic (does not absorb water). Silica glass can be doped with various materials. One purpose of doping is to raise the
refractive index (e.g. with
germanium dioxide (GeO2) or
aluminium oxide (Al2O3)) or to lower it (e.g. with
fluorine or
boron trioxide (B2O3)). Doping is also possible with laser-active ions (for example, rare-earth-doped fibers) in order to obtain active fibers to be used, for example, in fiber amplifiers or
laser applications. Both the fiber core and cladding are typically doped, so that the entire assembly (core and cladding) is effectively the same compound (e.g. an
aluminosilicate, germanosilicate, phosphosilicate or
borosilicate glass). Particularly for active fibers, pure silica is usually not a very suitable host glass, because it exhibits a low solubility for rare-earth ions. This can lead to quenching effects due to the clustering of dopant ions. Aluminosilicates are much more effective in this respect. Silica fiber also exhibits a high threshold for optical damage. This property ensures a low tendency for laser-induced breakdown. This is important for fiber amplifiers when utilized for the amplification of short pulses. Because of these properties, silica fibers are the material of choice in many optical applications, such as communications (except for very short distances with plastic optical fiber), fiber lasers, fiber amplifiers, and fiber-optic sensors. Large efforts put forth in the development of various types of silica fibers have further increased the performance of such fibers over other materials.
Fluoride glass Fluoride glass is a class of non-oxide optical quality glasses composed of
fluorides of various
metals. Because of the low
viscosity of these glasses, it is very difficult to completely avoid
crystallization while processing it through the glass transition (or drawing the fiber from the melt). Thus, although
heavy metal fluoride glasses (HMFG) exhibit very low optical attenuation, they are not only difficult to manufacture, but are quite fragile, and have poor resistance to moisture and other environmental attacks. Their best attribute is that they lack the absorption band associated with the
hydroxyl (OH) group (3,200–3,600 cm−1; i.e., 2,777–3,125 nm or 2.78–3.13 μm), which is present in nearly all oxide-based glasses. Such low losses were never realized in practice, and the fragility and high cost of fluoride fibers made them less than ideal as primary candidates. Fluoride fibers are used in mid-
IR spectroscopy,
fiber optic sensors,
thermometry, and
imaging. Fluoride fibers can be used for guided lightwave transmission in media such as YAG (
yttrium aluminium garnet)
lasers at 2.9 μm, as required for medical applications (e.g.
ophthalmology and
dentistry). An example of a heavy metal fluoride glass is the
ZBLAN glass group, composed of
zirconium,
barium,
lanthanum,
aluminium, and
sodium fluorides. Their main technological application is as optical waveguides in both planar and fiber forms. They are advantageous especially in the
mid-infrared (2,000–5,000 nm) range.
Phosphate glass Phosphate glass is a class of optical glasses composed of
metaphosphates of various metals. Instead of the SiO4
tetrahedra in the
network solid structure of silicate glasses, the building block for this glass is
phosphorus pentoxide (P2O5), which crystallizes in at least four different forms. The most familiar
polymorph is the cagelike structure of P4O10. Phosphate glasses can be advantageous over silica glasses for optical fibers with a high concentration of doping rare-earth ions. A mix of fluoride glass and phosphate glass is fluorophosphate glass.
Chalcogenide glass The
chalcogens—the elements in
group 16 of the periodic table—particularly
sulfur (S),
selenium (Se) and
tellurium (Te)—react with more
electropositive elements, such as
silver, to form
chalcogenides. These are extremely versatile compounds, in that they can be crystalline or amorphous, metallic or semiconducting, and conductors of
ions or
electrons.
Chalcogenide glass can be used to make fibers for far infrared transmission.
Process Preform Standard optical fibers are made by first constructing a large-diameter
preform with a carefully controlled refractive index profile, and then
pulling the preform to form the long, thin optical fiber. The preform is commonly made by three
chemical vapor deposition methods:
inside vapor deposition,
outside vapor deposition, and
vapor axial deposition. With
inside vapor deposition, the preform starts as a hollow glass tube approximately long, which is placed horizontally and rotated slowly on a
lathe. Gases such as
silicon tetrachloride (SiCl4) or
germanium tetrachloride (GeCl4) are injected with
oxygen in the end of the tube. The gases are then heated by means of an external hydrogen burner, bringing the temperature of the gas up to 1,900
K (1,600 °C, 3,000 °F), where the tetrachlorides react with oxygen to produce
silica or
germanium dioxide particles. When the reaction conditions are chosen to allow this reaction to occur in the gas phase throughout the tube volume, in contrast to earlier techniques where the reaction occurred only on the glass surface, this technique is called
modified chemical vapor deposition. The oxide particles then agglomerate to form large particle chains, which subsequently deposit on the walls of the tube as soot. The deposition is due to the large difference in temperature between the gas core and the wall causing the gas to push the particles outward in a process known as
thermophoresis. The torch is then traversed up and down the length of the tube to deposit the material evenly. After the torch has reached the end of the tube, it is then brought back to the beginning of the tube and the deposited particles are then melted to form a solid layer. This process is repeated until a sufficient amount of material has been deposited. For each layer the composition can be modified by varying the gas composition, resulting in precise control of the finished fiber's optical properties. In outside vapor deposition or vapor axial deposition, the glass is formed by
flame hydrolysis, a reaction in which silicon tetrachloride and germanium tetrachloride are oxidized by reaction with water in an
oxyhydrogen flame. In outside vapor deposition, the glass is deposited onto a solid rod, which is removed before further processing. In vapor axial deposition, a short
seed rod is used, and a porous preform, whose length is not limited by the size of the source rod, is built up on its end. The porous preform is consolidated into a transparent, solid preform by heating to about 1,800 K (1,500 °C, 2,800 °F). . Typical communications fiber uses a circular preform. For some applications such as
double-clad fibers another form is preferred. In
fiber lasers based on double-clad fiber, an asymmetric shape improves the
filling factor for
laser pumping. Because of the surface tension, the shape is smoothed during the drawing process, and the shape of the resulting fiber does not reproduce the sharp edges of the preform. Nevertheless, careful polishing of the preform is important, since any defects of the preform surface affect the optical and mechanical properties of the resulting fiber.
Drawing The preform, regardless of construction, is placed in a device known as a
drawing tower, where the preform tip is heated and the optical fiber is pulled out as a string. The tension on the fiber can be controlled to maintain the desired fiber thickness.
Cladding The light is guided down the core of the fiber by an optical cladding with a lower refractive index that traps light in the core through total internal reflection. For some types of fiber, the cladding is made of glass and is drawn along with the core from a preform with radially varying index of refraction. For other types of fiber, the cladding is made of plastic and is applied like a coating (see below).
Coatings The cladding is coated by a buffer, (not to be confused with an actual buffer tube), that protects it from moisture and physical damage. The thickness of the coating is taken into account when calculating the stress that the fiber experiences under different bend configurations. When a coated fiber is wrapped around a mandrel, the stress experienced by the fiber is given by Multi-fiber cable usually uses colored buffers to identify each strand. Modern cables come in a wide variety of sheathings and armor, designed for applications such as direct burial in trenches, high voltage isolation, dual use as power lines, installation in conduit, lashing to aerial telephone poles,
submarine installation, and insertion in paved streets. Some fiber optic cable versions are reinforced with
aramid yarns or glass yarns as an intermediary
strength member. In commercial terms, usage of the glass yarns are more cost-effective with no loss of mechanical durability. Glass yarns also protect the cable core against rodents and termites. == Practical issues ==