The Portneuf River watershed is a heavily used and anthropogenically altered system. After a series of heavy floods in the early 1960s the
Army Corps of Engineers designed and constructed a concrete channel to control flooding in 1965. The channelization followed the river's route and cut through the west side of
Pocatello, drastically altering the natural river processes. One common result of human activity is the loading of nutrients into the water system through both point and non-point sources. The river is subjected to use by four municipalities (
Lava Hot Springs,
McCammon,
Inkom, and Pocatello) over its length. The dynamic geology of the region and the heavy use by the local populations have produced a unique set of chemical characteristics associated with both the biological processes and the interactions with the local geology.
Nitrates Nutrient runoffs from intensive agriculture and ranching along the route of the river have noticeably increased the
nitrate loads in the stream. This is compounded by the addition of treated effluent from the city of Pocatello's
wastewater treatment facility and the waste associated with the
phosphate processing plant, Simplot. This increased nutrient load supports an increased
biomass within the system.
Carbon exchange The exchange of inorganic
carbon between the solid earth and the atmosphere in the Portneuf watershed has produced deposits of CaCO3 throughout the system. Known as
travertine and
tufa, these deposits are formed as a function of the dynamic groundwater and geology of the region. Tufa is known throughout the geologic collective as the soft and porous
CaCO3 deposits associated with moving freshwater environments. Travertine is a related deposit separated by the fact that it is associated with thermal waters. Deposition of tufa is complex, involving processes of
dissolution,
saturation,
subsurface transport, emergence and
precipitation. Both versions of precipitated CaCO3 are present in the Portneuf watershed. Several very different but related processes control the precipitation of CaCO3 in natural aqueous systems. The chemical processes are driven by the chemical properties of the elements and molecules involved. The physical processes are driven by characteristics of the watershed system (gradient, flow, substrate, groundwater flow properties). The biotic processes are driven by the activities of living organisms.
Chemical processes Calcium carbonate formations are associated with regions where meteoric waters become enriched with calcium carbonate by direct dissolution of CaCO3-rich rocks underground only to resurface and re-precipitate
calcite. It is well known that the geology of the Portneuf watershed contains large thicknesses of
limestone and
dolomite strata that are mostly
Paleozoic. Enrichment of CaCO3 in the meteoric waters is due to the addition of CO2 either through interaction with the atmosphere, or infiltrating through organic compound containing soil layers. This saturation of CO2 in the groundwater allows for the dissolution of carbonate rocks as it drives pH down. and is a relevant explanation for at least some formation through the region, especially through the town site of Lava Hot Springs. The figure below is a schematic representation of the stream gradient of the Portneuf from just below Chesterfield Reservoir and above American Falls Reservoir adapted from Minshall, 1973.
Biotic processes The third recognized mechanism for tufa development is the active role played by the biota.
Algae and
mosses, along with higher plants and some insects, often trap tiny particles within their sinuous roots, fronds, and shelter/feeding structures, acting as nucleation points for further precipitation. This may explain some of the deposition locations, but the biota plays a larger role as photosynthetic plants remove CO2 from the water, further concentrating the Ca2+ and CO32− and driving precipitation. The Portneuf through this reach is rich in plant life not only due to the nutrient accumulation as it travels through farmland but from the warm water inputs that protect the stream from the effects of the harsh cold of winter temperatures. This could be a mechanism for potentially increasing tufa formation through the reach. An interesting study completed in 1972 showed evidence that the development of tufa and travertine filled the interstices normally found on the rocky river. This had implications for some burrowing organisms as well as nutrient cycling. Precipitation of tufa in the Portneuf drainage is produced through the combination of four complex mechanisms: dissolution of limestones by meteoric waters containing carbonic acids, degassing of CO2 at turbulent sites, the removal of CO2 by photosynthetic plants, and the trapping of particles of CaCO3 by the biota. The complex interactions between these different mechanisms may never be fully understood but offer insight into the occurrence of formations. ==See also==