The main geological formation underlying the Pymmes Brook catchment area is
Eocene London Clay. The uppermost part of this formation - the "
Claygate Beds" - has a higher sand content. In some parts of the higher sections of the catchment area, the London Clay is overlain by "Stanmore Gravel" (also known as "Pebble Gravel") and "Dollis Hill Gravel" (both
Quaternary pre-glacial fluvial deposits), and by Quaternary glacial
till. From Oak Hill Park southwards, there are sand, gravel and alluvium deposits on the Pymmes Brook valley floor. And east of Palmers Green, the brook crosses extensive Quaternary river terrace deposits laid down by the
River Lea. As a west bank tributary of the lower River Lea, Pymmes Brook came into being about 400,000 years ago, after the
Anglian glaciation. During that glaciation, ice from the north of England advanced at least as far south as
Watford,
Finchley and
Chingford. Until the Anglian glaciation, the
River Thames flowed north-eastwards via Watford, through what is now the
Vale of St Albans, then eastwards towards
Chelmsford and the
North Sea. As a result of the glaciation, the Thames was diverted to a more southerly route, broadly along the line of its current course. Prior to the Anglian glaciation, a "proto-Mole-Wey" river was flowing northwards from the
Weald and
North Downs, through the "
Finchley depression" and
Palmers Green, to join the proto-Thames somewhere around
Hoddesdon, at what is today an altitude of around 60 metres. It was this river which, during the course of the early and middle
Pleistocene, deposited the "Dollis Hill Gravel" at successive altitudes. When the Anglian ice sheet diverted the Thames southwards, the Mole-Wey was cut off at
Richmond. Meltwater from the retreating Anglian ice sheet gave birth to a south-flowing
lower River Lea, and that river cut into and followed in part the line of the former proto-Mole-Wey. It flowed into the newly diverted Thames, which at that time was spread over a wide flood plain extending as far north as
Islington. And, as the ice sheet retreated, west bank tributaries of the lower Lea, such as Pymmes Brook, flowed eastwards and south-eastwards from higher ground running roughly south–north through
Potters Bar, down towards the newly formed lower River Lea. They (and their own tributaries such as Bounds Green Brook) cut down successively through till left by the ice sheet, then through "Dollis Hill Gravel", and then into Eocene London Clay below. It is not known at present whether Pymmes Brook, and other west bank tributaries such as
Salmons Brook and
Cuffley Brook, followed valleys which had been in existence before the ice sheet covered the land, or whether they fashioned a substantially different landscape after the ice retreated. But it is known that today's tributaries of the upper Lea, such as the Rivers
Mimram and
Stort, follow broadly the same lines as pre-glaciation valleys, so, by analogy, it is quite possible that elements at least of the pre-glaciation topography of the lower Lea basin are reflected in today's relief. In the case of Pymmes Brook immediately after the glaciation, that stream joined the River Lea somewhere around
Broomfield Park, where there is a deposit of "Boyn Hill Gravel".) Pymmes Brook thus extended its course eastwards from Broomfield Park, across the valley floor of the lower Lea, through
Upper Edmonton, to
Meridian Water. From
Cockfosters down to
Arnos Park, Pymmes Brook, like the
lower River Lea, has a notably steep eastern slope. Associated with that is the fact that almost all the tributaries of that section of Pymmes Brook are on its west side. So it is possible that that section of the brook has, like the lower River Lea, also shifted eastwards somewhat since the Anglian glaciation (and, if so, presumably for the same reason). In addition, that section of the Pymmes Brook valley today seems disproportionately deep for such a small stream – for example, at Cat Hill. But we are currently in an interglacial period, and the stream would have been flowing more strongly than today at times of "high discharge, under cold climatic conditions". And, at such times, soil cover and vegetation would have been much thinner than today, thus facilitating greater erosion. Furthermore, as the River Lea itself cut down as it moved eastwards, it lowered the base level of its tributary stream, Pymmes Brook. That would have enabled the brook to become further incised into the higher ground to the west of the Lea flood plain. The drainage pattern in this area continues to evolve. For example, the pronounced
wind gap at the junction of Waggon Road and the A111, where Monken Mead Brook turns sharply to the south to become the upper part of Pymmes Brook, indicates that Monken Mead Brook once continued eastwards as a tributary of Salmons Brook. It has been captured by Pymmes Brook in the recent geological past. ==Parks==