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Quasi-phase-matching

Quasi-phase-matching is a technique in nonlinear optics which allows a positive net flow of energy from the pump frequency to the signal and idler frequencies by creating a periodic structure in the nonlinear medium. Momentum is conserved, as is necessary for phase-matching, through an additional momentum contribution corresponding to the wavevector of the periodic structure. Consequently, in principle any three-wave mixing process that satisfies energy conservation can be phase-matched. For example, all the optical frequencies involved can be collinear, can have the same polarization, and travel through the medium in arbitrary directions. This allows one to use the largest nonlinear coefficient of the material in the nonlinear interaction.

Mathematical description
In nonlinear optics, the generation of new frequencies is the result of the nonlinear polarization response of the crystal due to a typically monochromatic high-intensity pump frequency. When the crystal axis is flipped, the polarization wave is shifted by 180°, thus ensuring that there is a positive energy flow to the signal and idler beam. In the case of sum-frequency generation, where waves at frequencies \omega_1 and \omega_2 are mixed to produce \omega_3=\omega_1+\omega_2, the polarization equation can be expressed by : P_3 = 4 d A_1 A_2 e^{i(k_1+k_2)z}, where d is the nonlinear susceptibility coefficient, i represents the imaginary unit, A are the complex-valued amplitudes, and k=\omega/c is the wavenumber. In this frequency domain vector representation, the sign of the d coefficient is flipped when the nonlinear (anisotropic) crystal axis is flipped, : P_3 = -4d A_1 A_2 e^{i(k_1+k_2)z} = 4d A_1 A_2 e^{i((k_1+k_2)z} e^{i\pi}. ==Development of signal amplitude==
Development of signal amplitude
Let us compute the nonlinearly-generated signal amplitude in the case of second harmonic generation, where a strong pump at \omega_1 produces a frequency-doubled signal at \omega_2=2\omega_1, assuming a constant pump amplitude (undepleted pump approximation). The signal wavelength can be expressed as a sum over the number of domains that exist in the crystal. In general the spatial rate of change of the signal amplitude is \frac{\partial A_2}{\partial z}=A_1^2 \chi e^{i \Delta k z}, where A_2 is the generated frequency amplitude and A_1 is the pump frequency amplitude and \Delta k is the phase mismatch between the two optical waves. The \chi refers to the nonlinear susceptibility of the crystal. In the case of a periodically poled crystal the crystal axis is flipped by 180 degrees in every other domain, which changes the sign of \chi. For the n^{th} domain \chi can be expressed as \chi=\chi_0 (-1)^n where n is the index of the poled domain. The total signal amplitude A_2 can be expressed as a sum A_2=A_1^2 \chi_0 \sum^{N-1}_{n=0} (-1)^n \int^{\Lambda (n+1)}_{\Lambda n} e^{i \Delta k z} \partial z where \Lambda is the spacing between poles in the crystal. The above equation integrates to A_2=-\frac{i A_1^2 \chi_0}{\Delta k} \sum^{N-1}_{n=0} (-1)^n (e^{i \Delta k \Lambda (n+1)}-e^{i \Delta k \Lambda n}) and reduces to A_2=-i A_1^2 \chi_0 \frac{e^{i \Delta k \Lambda}-1}{\Delta k} \sum^{N-1}_{n=0} (-1)^n e^{i \Delta k \Lambda n} The summation yields s=\sum^{N-1}_{n=0} (-1)^n e^{i \Delta k \Lambda n}=1-e^{i \Delta k \Lambda}+e^{i 2 \Delta k \Lambda}-e^{i 3 \Delta k \Lambda}+...+(-1)^N e^{i \Delta k \Lambda (N-2)}-(-1)^N e^{i \Delta k \Lambda (N-1)}. Multiplying both sides of the above equation by a factor of e^{i \Delta k \Lambda} leads to s e^{i \Delta k \Lambda}=e^{i \Delta k \Lambda} -e^{i 2 \Delta k \Lambda}+e^{i 3 \Delta k \Lambda}+...+(-1)^N e^{i \Delta k \Lambda (N-1)}-(-1)^N e^{i \Delta k \Lambda N}. Adding both equation leads to the relation s(1+e^{i \Delta k \Lambda})=1-(-1)^N e^{i \Delta k \Lambda N}. Solving for s gives s=\frac{1-(-1)^N e^{i \Delta k \Lambda N} }{1+e^{i \Delta k \Lambda}}, which leads to A_2=-i A_1^2 \chi_0 \left( \frac{e^{i \Delta k \Lambda}-1}{\Delta k} \right)\left(\frac{1-(-1)^N e^{i \Delta k \Lambda N}}{e^{i \Delta k \Lambda}+1}\right). The total SHG intensity can be expressed by I_2=A_2 A_2^*= \left|A_{1}\right|^{4} \chi_0^2 \Lambda^2 \mbox{sinc}^2(\Delta k \Lambda/2) \left(\frac{1-(-1)^N \cos(\Delta k \Lambda N)}{1+\cos(\Delta k \Lambda)} \right). For the case of \Lambda=\frac{\pi}{\Delta k} the right part of the above equation is undefined so the limit needs to be taken when \Delta k \Lambda \rightarrow \pi by invoking L'Hôpital's rule. \lim_{\Delta k \Lambda\to\pi}\frac{1-(-1)^N \cos(\Delta k \Lambda N)}{1+\cos(\Delta k \Lambda)}=N^2 Which leads to the signal intensity I_2=\frac{4 \left|A_{1}\right|^{4} \chi_0^2 L^2}{\pi^2}. In order to allow different domain widths, i.e. \Lambda=\frac{m \pi}{\Delta k}, for m=1,3,5,..., the above equation becomes I_2=A_2 A_2^*= \left|A_{1}\right|^{4}\chi_0^2 \Lambda^2 \mbox{sinc}^2(m \Delta k \Lambda/2) \left(\frac{1-(-1)^N \cos(m \Delta k \Lambda N)}{1+\cos(m \Delta k \Lambda)} \right). With \Lambda = \frac{m \pi}{\Delta k} the intensity becomes I_2=\frac{4 \left|A_{1}\right|^{4} \chi_0^2 L^2}{m^2 \pi^2}. This allows quasi-phase-matching to exist at different domain widths \Lambda. From this equation it is apparent, however, that as the quasi-phase match order m increases, the efficiency decreases by m^2 . For example, for 3rd order quasi-phase matching only a third of the crystal is effectively used for the generation of signal frequency, as a consequence the amplitude of the signal wavelength only third of the amount of amplitude for same length crystal for 1st order quasi-phase match. ==Calculation of domain width==
Calculation of domain width
The domain width is calculated through the use of Sellmeier equation and using wavevector relations. In the case of DFG this relationship holds true \Delta k = k_1 - k_2 - k_3, where k_1, k_2, \mbox{and } k_3 are the pump, signal, and idler wavevectors, and k_i = \frac{2 \pi n(\lambda_i)}{\lambda_i}. By calculating \Delta k for the different frequencies, the domain width can be calculated from the relationship \Lambda = \frac{\pi}{\Delta k}. == Orthogonal quasi-phase-matching ==
Orthogonal quasi-phase-matching
This method enables the generation of high-purity hyperentangled two-photon state. In orthogonal quasi-phase matching (OQPM), a thin-layered crystal structure is combined with periodic poling along orthogonal directions. By combining periodic down-conversion of orthogonally polarized photons along with periodic poling that corrects the phase mismatch, the structure self corrects for longitudinal walk-off (delay) as it happens and before it accumulates. The superimposed spontaneous parametric downconversion (SPDC) radiation of the superlattice creates high-purity two-photon entangled state. ==References==
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