After graduating, in 1946, he took postdoctoral positions first at the
National Research Council (Canada), followed by the
University of North Carolina. He received his first faculty appointment at the
Polytechnic Institute of Brooklyn. In 1952, at the
University of North Carolina, he developed
Rice–Ramsperger–Kassel–Marcus (RRKM) theory by combining the former RRK theory with the
transition state theory. In 1964, he taught at the
University of Illinois. His approach to solving a problem is to "go full tilt." Marcus moved to the
California Institute of Technology in 1978.
Marcus theory of electron transfer Electron transfer is one of the simplest forms of a chemical reaction. It consists of one
outer-sphere electron transfer between substances of the same atomic structure likewise to Marcus’s studies between divalent and trivalent iron ions. Electron transfer may be one of the most basic forms of chemical reaction but without it life cannot exist. Electron transfer is used in all
respiratory functions as well as
photosynthesis. In the process of
oxidizing food molecules, two hydrogen ions, two electrons, and half an oxygen molecule react to make an
exothermic reaction as well as a water molecule: : 2 H+ + 2 e− + ½ O2 → H2O + heat Because electron transfer is such a broad, common, and essential reaction within nature, Marcus's theory has become vital within the field of chemistry and
biochemistry. A type of chemical reaction linked to his many studies of electron transfer would be the transfer of an electron between metal ions in different states of oxidation. An example of this type of chemical reaction would be one between a divalent and a trivalent iron ion in an aqueous solution. In Marcus's time chemists were astonished at the slow rate in which this specific reaction took place. This attracted many chemists in the 1950s and is also what began Marcus's interests in electron transfer. Marcus made many studies based on the principles that were found within this chemical reaction, and through his studies was able to elaborate his electron transfer theory. His approach gave way to new experimental programs that contributed to all branches within chemistry and biochemistry. As of his 100th birthday, he is still active doing research. == Honours and awards ==