Byproduct resin 1.1 dichloroethyl, a monomer of Polyvinylidene chloride (PVDC) was discovered at
Dow Chemical Company (Michigan, United States) in 1933 when a lab worker, Ralph Wiley, was having trouble washing beakers used in his process of developing a dry-cleaning product,
perchloroethylene. It was waterproof, strong and versatile; it could be rolled, forged, drawn, welded, stamped and blown. It was initially developed into a product when a division of
General Motors requested a flexible film to prevent corrosion on machine guns shipped overseas. Dow trademarked "Saran" in 1940, but the company did not immediately develop the product commercially. In 1942, fused layers of original-specification PVDC were used to make woven mesh ventilating insoles for newly developed
jungle or tropical combat boots made of rubber and canvas. These insoles were tested by experimental Army units in jungle exercises in Panama, Venezuela, and other countries, where they were found to increase the flow of dry outside air to the insole and base of the foot, reducing blisters and tropical ulcers. both employed by Dow Chemical Company, finished the last requirements needed for the introduction of PVDC, which was formulated in 1939 and monofilaments extruded initially. They also eliminated its green hue and offensive odor. A common
folk etymology holds that "saran" was formed from John Reilly's wife's and daughter's names, Sarah and Ann Reilly. In fact, Dow researchers could not come up with sufficiently appealing names to market the product. Dow instead decided to use
Firestone's name for plastic
streetcar seats, and purchased the naming rights. Saran Wrap and other Dow consumer products were acquired by
S. C. Johnson & Son in 1998. ==Formulation change to polyethylene==