featuring a wet-bulb thermometer Wet-bulb temperature is measured using a
thermometer that has its bulb wrapped in cloth—called a
sock—that is kept wet with distilled water via
wicking action. Such an instrument is called a
wet-bulb thermometer. A widely used device for measuring wet- and dry-bulb temperature is a
sling psychrometer, which consists of a pair of mercury bulb thermometers, one with a wet "sock" to measure the wet-bulb temperature and the other with the bulb exposed and dry for the dry-bulb temperature. The thermometers are attached to a swivelling handle, which allows them to be whirled around so that water evaporates from the sock and cools the wet bulb until it reaches
thermal equilibrium. An actual wet-bulb thermometer reads a temperature that is slightly different from the thermodynamic wet-bulb temperature, but they are very close in value. This is due to a coincidence: for a water-air system the
psychrometric ratio (see below) happens to be close to 1, although for systems other than air and water they might not be close. To understand why this is so, first consider the calculation of the thermodynamic wet-bulb temperature.
Experiment 1 In this case, a stream of unsaturated air is cooled. The heat from cooling that air is used to evaporate some water which increases the humidity of the air. At some point the air becomes saturated with water vapor (and has cooled to the thermodynamic wet-bulb temperature). In this case we can write the following balance of energy per mass of dry air: (H_\mathrm{sat} - H_0) \cdot \lambda = (T_0 - T_\mathrm{sat}) \cdot c_\mathrm{s} • H_\mathrm{sat} saturated water content of the air (kgH2O/kgdry air) • H_0 initial water content of the air (same unit as above) • \lambda latent heat of water (J/kgH2O) • T_0 initial air temperature (K) • T_\mathrm{sat} saturated air temperature (K) • c_s specific heat of air (J/kg·K)
Experiment 2 For the case of the wet-bulb thermometer, imagine a drop of water with unsaturated air blowing over it. As long as the vapor pressure of water in the drop (function of its temperature) is greater than the partial pressure of water vapor in the air stream, evaporation will take place. Initially, the heat required for the evaporation will come from the drop itself. Instead, as the drop starts cooling, it is now colder than the air, so convective heat transfer begins to occur from the air to the drop. Furthermore, the evaporation rate depends on the difference of concentration of water vapor between the drop-stream interface and the distant stream (i.e. the "original" stream, unaffected by the drop), and on a convective mass transfer coefficient, which is a function of the components of the mixture (i.e. water and air). After a certain period, an equilibrium is reached: the drop has cooled to a point where the rate of heat carried away in evaporation is equal to the heat gain through convection. At this point, the following balance of energy per interface area is true: (H_\mathrm{sat} - H_0) \cdot \lambda \cdot k' = (T_0 - T_\mathrm{eq}) \cdot h_\mathrm{c} • H_\mathrm{sat} water content of interface at equilibrium (kgH2O/kgdry air) (note that the air in this region is and has always been saturated) • H_0 water content of the distant air (same unit as above) • k'
mass transfer coefficient (kg/m2⋅s) • T_0 air temperature at distance (K) • T_\mathrm{eq} water drop temperature at equilibrium (K) • h_\mathrm{c} convective heat transfer coefficient (W/m2·K) Note that: • (H - H_0) is the
driving force for mass transfer (constantly equal to H_\mathrm{sat} - H_0 throughout the entire experiment) • (T_0 - T) is the
driving force for heat transfer (when T reaches T_\mathrm{eq}, the equilibrium is reached) Let us rearrange that equation into: (H_\mathrm{sat} - H_0) \cdot \lambda = (T_0 - T_\mathrm{eq}) \cdot \frac{h_\mathrm{c}}{k'} Now let's go back to our original "thermodynamic wet-bulb" experiment, Experiment 1. If the air stream is the same in both experiments (i.e. H_0 and T_0 are the same), then we can equate the right-hand sides of both equations: (T_0 - T_\mathrm{sat}) \cdot c_\mathrm{s} = (T_0 - T_\mathrm{eq}) \cdot \frac{h_\mathrm{c}}{k'} Rearranging: T_0 - T_\mathrm{sat} = (T_0 - T_\mathrm{eq}) \cdot \frac{h_\mathrm{c}}{k' \cdot c_\mathrm{s}} If \dfrac{h_\mathrm{c}}{k' c_\mathrm{s}} = 1 then the temperature of the drop in Experiment 2 is the same as the wet-bulb temperature in Experiment 1. Due to a coincidence, for the mixture of air and water vapor this is the case, the ratio (called
psychrometric ratio) being close to 1. Experiment 2 is what happens in a common wet-bulb thermometer, meaning that its reading is fairly close to the thermodynamic ("real") wet-bulb temperature. Experimentally, the wet-bulb thermometer reads closest to the thermodynamic wet-bulb temperature if: • The sock is shielded from radiant heat exchange with its surroundings • Air flows past the sock quickly enough to prevent evaporated moisture from affecting evaporation from the sock • The water supplied to the sock is at the same temperature as the thermodynamic wet-bulb temperature of the air In practice the value reported by a wet-bulb thermometer differs slightly from the thermodynamic wet-bulb temperature because: • The sock is not perfectly shielded from radiant heat exchange • Air flow rate past the sock may be less than optimum • The temperature of the water supplied to the sock is not controlled At relative
humidities below 100 percent, water
evaporates from the bulb, cooling it below ambient temperature. To determine relative humidity, ambient temperature is measured using an ordinary thermometer, better known in this context as a
dry-bulb thermometer. At any given ambient temperature, less relative humidity results in a greater difference between the dry-bulb and wet-bulb temperatures; the wet-bulb is colder. The precise relative humidity is determined by reading from a
psychrometric chart of wet-bulb versus dry-bulb temperatures, or by calculation.
Psychrometers are instruments with both a wet-bulb and a dry-bulb thermometer. A wet-bulb thermometer can also be used outdoors in sunlight in combination with a
globe thermometer (which measures the incident
radiant temperature) to calculate the
wet-bulb globe temperature (WBGT). == Adiabatic wet-bulb temperature ==