Segnitite

The mineral segnitite is a part of the alunite-jarosite family which is a part of the alunite supergroup, which has a general formula of . Minerals in the alunite-jarosite family have the general formula . More specifically, Segnitite is a part of the low-S lusungite group of alunite-jarosite minerals. The lusungite group falls on the lower third of the ternary diagram, with the jarosite group on top, having the highest content of sulfur. The beudantite-corkite group lies in the middle third on the ternary diagram, possessing intermediate amounts of sulfur. The lusungite group then has the lowest amount of sulfur, and has end members segnitite and lusungite, which then have varying amounts of arsenic to phosphorus; segnitite is the arsenic rich end member of the lusugnite group. Through electron microprobe analysis on the basis of 14 oxygen atoms, the empirical formula of segnitite was found to be . Four alternative and simplified versions include: (1) , (2) , (3) , (4) , although the preferred formula is , which is most consistent with the space group (Rm) for Segnitite. ==Crystal structure and habit==

Segnitite belongs to the trigonal crystal system, which is also a subcategory of the hexagonal crystal system. Segnitite occurs most commonly as rhombohedral crystals that can grow to around 5mm in height and as pseudo-octahedral crystals that typically measure about 1mm across. The habit of these segnitite clusters is often found to be hemispherical in shape. Rhombohedron {112} and Pinacoid {001} are the two most common forms of segnitite. ==Occurrence==

Segnitite was first discovered in Broken Hill ore deposit in Broken Hill, New South Wales, Australia. It was first found in the oxidized zone of lead and zinc sulfide ores bodies of the Broken Hill ore deposit and forms in similar settings around the world. Segnitite is a relatively uncommon mineral, and it not found in very large quantities, but is found worldwide in similar areas. Segnitite has since been found in many localities in Western Europe, specifically in sites near Switzerland, Germany and Austria. Segnitite is commonly found alongside many well known minerals including anglesite, galena, jamesonite, linarite, arsenopyrite, cerussite, covellite, cuprite, sphalerite, sulfur, beudantite, cassiterite, pyrite, smithsonite, carminite and plumbojarosite. Many of these minerals are important ore minerals. Segnitite poses some importance when considering the overall composition of surrounding rock. ==Crystallography==

Through X-ray diffraction (XRD), which is either conducted through powder diffraction, or through single-crystal X-ray analysis, segnitite was found to belong to the hexagonal crystal system of minerals. Using angles 2θ< 66 degrees, cell parameters were estimated along with chemical composition. Before segnitite was identified as a mineral, it was commonly mistaken for beudantite. There are close similarities in diffraction data when comparing low sulfate beundantite from the beudantite-corkite group, and segnitite of the lusungnite group. Beundantite, segnitite and plumbojarosite form solid solutions with each other; conditions that form these minerals are similar. The space group Rm was determined for segnitite as the best fit based on the space group of beudantite, R3m as there is no well observed crystal structure. The difference between segnitite and beundantite is the replacement of the sulfate anion in beundantite with an arsenate anion to form segnitite. ==Optical properties==

Segnitite exhibits weak pleochroism from a pale yellow to a more moderate yellow under different angles of plane polarized light, although the effects can be much more dramatic under polarized light. Dichroism and trichroism are both types of pleochroism. The term dichroism is used to describe optical properties of minerals that are uniaxial, including segnitite. Minerals that exhibit dichroism are generally trigonal, hexagonal and tetragonal. A response from UV light was not observed from segnitite. ==References==