Radioluminescent paint is a self-luminous paint that consists of a small amount of a
radioactive isotope (
radionuclide) mixed with a
radioluminescent phosphor chemical. The radioisotope continually decays, emitting radiation particles which strike molecules of the phosphor, exciting them to emit visible light. The isotopes selected are typically strong emitters of
beta radiation, preferred since this radiation will not penetrate an enclosure. Radioluminescent paints will glow without exposure to light until the radioactive isotope has decayed (or the phosphor degrades), which may be many years. Because of safety concerns and tighter regulation, consumer products such as clocks and watches now increasingly use phosphorescent rather than radioluminescent substances. Previously radioluminicesent paints were used extensively on watch and clock dials and known colloquially to watchmakers as "clunk". Radioluminescent paint may still be preferred in specialist applications, such as
diving watches.
Radium to increase luminescence Radioluminescent paint was invented in 1908 by
Sabin Arnold von Sochocky and originally incorporated
radium-226. Radium paint was widely used for 40 years on the faces of watches, compasses, and aircraft instruments, so they could be read in the dark. Radium is a
radiological hazard, emitting
gamma rays that can penetrate a glass watch dial and into human tissue. During the 1920s and 1930s, the harmful effects of this paint became increasingly clear. A notorious case involved the "
Radium Girls", a group of women who painted watchfaces and later suffered adverse health effects from ingestion, in many cases resulting in death. In 1928, Dr von Sochocky himself died of aplastic anemia as a result of radiation exposure.
Tritium tritium vials are simply tritium gas-filled, thin glass vials with inner surfaces coated with a
phosphor. The "gaseous tritium light source" vial shown here is brand new. The latest generation of the radioluminescent materials is based on
tritium, a radioactive isotope of
hydrogen with half-life of 12.32 years that emits very low-energy beta radiation. The devices are similar to a
fluorescent tube in construction, as they consist of a hermetically sealed (usually borosilicate-glass) tube, coated inside with a phosphor, and filled with tritium. They are known under many names – e.g. gaseous tritium light source (GTLS), traser, betalight. Tritium light sources are most often seen as "permanent" illumination for the hands of
wristwatches intended for diving, nighttime, or tactical use. They are additionally used in glowing
novelty keychains, in self-illuminated
exit signs, and formerly in fishing lures. They are favored by the military for applications where a power source may not be available, such as for instrument
dials in aircraft,
compasses, lights for map reading, and sights for weapons. Tritium lights are also found in some old
rotary dial telephones, though due to their age they no longer produce a useful amount of light. == See also ==