The electrical characteristics, and the temperature and frequency behavior of film capacitors are essentially determined by the type of material that forms the dielectric of the capacitor. The following table lists the most important characteristics of the principal plastic film materials in use today. Characteristics of mixed film materials are not listed here. The figures in this table are extracted from specifications published by various different manufacturers of film capacitors for industrial electronic applications. The large range of values for the dissipation factor includes both typical and maximum specifications from data sheets of the various manufacturers. Typical electrical values for power and large AC capacitors were not included in this table.
Polypropylene (PP) film capacitors Polypropylene film capacitors have a dielectric made of the thermoplastic, non-polar, organic and partially crystalline polymer material Polypropylene (PP), trade name Treofan, from the family of
polyolefins. They are manufactured both as metallized wound and stacked versions, as well as film/foil types. Polypropylene film is the most-used dielectric film in industrial capacitors and also in power capacitor types. The polypropylene film material absorbs less moisture than polyester film and is therefore also suitable for "naked" designs without any coating or further packaging. But the maximum temperature of 105 °C hinders use of PP films in SMD packaging. The temperature and frequency dependencies of electrical parameters for polypropylene film capacitors are very low. Polypropylene film capacitors have a linear,
negative temperature coefficient of capacitance of ±2,5 % within their temperature range. Therefore, polypropylene film capacitors are suitable for applications in Class 1 frequency-determining circuits, filters, oscillator circuits, audio circuits, and timers. They are also useful for compensation of inductive coils in precision filter applications, and for high-frequency applications. In addition to the application class qualification for the film/foil version of PP film capacitors, the standard IEC/EN 60384-13 specifies three "stability classes". These stability classes specify the tolerance on temperature coefficients together with the permissible change of capacitance after defined tests. They are divided into different temperature coefficient grades (α) with associated tolerances and preferred values of permissible change of capacitance after mechanical, ambient (moisture) and life time tests. The table is not valid for capacitance values smaller than 50 pF. In addition, PP film capacitors have the lowest
dielectric absorption, which makes them suitable for applications such as
VCO timing capacitors,
sample-and-hold applications, and audio circuits. They are available for these precision applications in very narrow capacitance tolerances. The dissipation factor of PP film capacitors is smaller than that of other film capacitors. Due to the low and very stable dissipation factor over a wide temperature and frequency range, even at very high frequencies, and their high dielectric strength of 650 V/μm, PP film capacitors can be used in metallized and in film/foil versions as capacitors for pulse applications, such as CRT-scan deflection circuits, or as so-called "
snubber" capacitors, or in
IGBT applications. In addition, polypropylene film capacitors are used in AC power applications, such as motor run capacitors or
power-factor correction (PFC) capacitors. Polypropylene film capacitors are widely used for
EMI suppression, including direct connection to the power supply mains. In this latter application, they must meet special testing and certification requirements concerning safety and non-flammability. Most power capacitors, the largest capacitors made, generally use polypropylene film as the dielectric. PP film capacitors are used for high-frequency high-power applications such as
induction heating, for pulsed power energy discharge applications, and as AC capacitors for electrical distribution. The AC voltage ratings of these capacitors can range up to 400 kV. The relatively low permittivity of 2.2 is a slight disadvantage, and PP film capacitors tend to be somewhat physically larger than other film caps. The capacitor grade films are produced up to 20 μm in thickness with width of roll up to 140 mm. Rolls are carefully vacuum packed in pairs according to the specifications required for the capacitor.
Polyester (PET) film capacitors Polyester film capacitors are film capacitors using a dielectric made of the thermoplastic polar polymer material
polyethylene terephthalate (PET), trade names Hostaphan or
Mylar, from the polyester family. They are manufactured both as metallized wound and stacked versions, as well as film/foil types. The polyester film adsorbs very little moisture, and this feature makes it suitable for "naked" designs without any further coating needed. They are the low-cost mass-produced capacitors in modern electronics, featuring relatively small dimensions with relatively high capacitance values. PET capacitors are mainly used as general purpose capacitors for DC applications, or for semi-critical circuits with operating temperatures up to 125 °C. The maximum temperature rating of 125 °C also allows
SMD film capacitors to be made with PET films. The low cost of polyester and the relatively compact dimensions are the main reasons for the high prevalence of PET film capacitors in modern designs. The small physical dimensions of PET film capacitors are the result of a high relative permittivity of 3.3, combined with a relatively high dielectric strength leads to a relatively high
volumetric efficiency. This advantage of compactness comes with some disadvantages. The capacitance temperature dependence of polyester film capacitors is relatively high compared to other film capacitors, ±5% over the entire temperature range. The capacitance frequency dependence of polyester film capacitors compared with the other film capacitors is -3% in the range from 100 Hz to 100 kHz at the upper limit. Also, the temperature and frequency dependence of the
dissipation factor are higher for polyester film capacitors compared with the other film capacitor types. Polyester film capacitors are mainly used for general purpose applications or semi-critical circuits with operating temperatures up to 125 °C.
Polyethylene naphthalate (PEN) film capacitors Polyethylene naphthalate film capacitors are film capacitors using a dielectric made of the thermoplastic biaxial polymer material polyethylene naphthalate (PEN), trade names Kaladex, Teonex. They are produced only as metallized types. PEN, like PET, belongs to the polyester family, but has better stability at high temperatures. Therefore, PEN film capacitors are more suitable for high temperature applications and for SMD packaging. The temperature and frequency dependence of the electrical characteristics for capacitance and dissipation factor of PEN film capacitors are similar to the PET film capacitors. Because of the smaller relative permittivity and lower dielectric strength of the PEN polymer, PEN film capacitors are physically larger for a given capacitance and rated voltage value. In spite of this, PEN film capacitors are preferred over PET when the ambient temperature during operation of the capacitors is permanently above 125 °C. The special PEN "high voltage" (HV) dielectric offers excellent electrical properties during the life tests at high voltages and high temperatures (175 °C). PEN capacitors are mainly used for non-critical filtering, coupling and decoupling in electronic circuits, when the temperature dependencies do not matter.
Polyphenylene sulfide (PPS) film capacitors Polyphenylene sulfide film capacitors are film capacitors with dielectric made of the thermoplastic, organic, and partially crystalline polymer material
Poly(p-phenylene sulfide) (PPS), trade name Torelina. They are only produced as metallized types. The temperature dependence of the capacitance of PPS film capacitors over the entire temperature range is very small (± 1.5%) compared with other film capacitors. Also the frequency dependence in the range from 100 Hz to 100 kHz of the capacitance of the PPS film capacitors is ± 0.5%, very low compared with other film capacitors. The dissipation factor of PPS film capacitors is quite small, and the temperature and frequency dependence of the dissipation factor over a wide range is very stable. Only at temperatures above 100 °C does the dissipation factor increase to larger values. The
dielectric absorption performance is excellent, behind only PTFE and PS dielectric capacitors. Polyphenylene sulfide film capacitors are well-suited for applications in frequency-determining circuits and for high-temperature applications. Because of their good electrical properties, PPS film capacitors are an ideal replacement for polycarbonate film capacitors, whose production since 2000 has been largely discontinued. In addition to their excellent electrical properties, PPS film capacitors can withstand temperatures up to 270 °C without damaging the film quality, so that PPS film capacitors are suitable for surface mount devices (SMD), and can tolerate the increased reflow soldering temperatures for lead-free soldering mandated by the
RoHS 2002/95/EC directive. Cost of a PPS film capacitor is usually higher compared to a PP film capacitor.
Polytetrafluoroethylene (PTFE) film capacitors Polytetrafluoroethylene film capacitors are made with a dielectric of the synthetic fluoropolymer polytetrafluoroethylene (PTFE), a hydrophobic solid
fluorocarbon. They are manufactured both as metallized and as film/foil types, although poor adherence to the film makes metallization difficult. PTFE is often known by the
DuPont trademark
Teflon. Polytetrafluoroethylene film capacitors feature a very high temperature resistance up to 200 °C, and even further up to 260 °C, with a voltage derating. The dissipation factor 2 • 10 −4 is quite small. The change in capacitance over the entire temperature range of +1% to -3% is a little bit higher than for polypropylene film capacitors. However, since the smallest available film thickness for PTFE films is 5.5 μm, approximately twice of the thickness of polypropylene films, the PTFE film capacitors are physically bulkier than PP film capacitors. It added that the film thickness on the surface is not constant, so that Teflon films are difficult to produce. Therefore, the number of manufacturers of PTFE film capacitors is limited. PTFE film capacitors are available with rated voltages of 100 V to 630 V DC. They are used in military equipment, in aerospace, in geological probes, in burn-in circuits and in high-quality audio circuits. Main producers of PTFE film capacitors are located in the USA.
Polystyrene (PS) film capacitors Polystyrene film capacitors, sometimes known as "Styroflex Capacitors", were well known for many years as inexpensive film capacitors for general purpose applications, in which high capacitance stability, low dissipation factor and low leakage currents were needed. But because the film thickness could be not made thinner than 10 μm, and the maximum temperature ratings reached only 85 °C, the PS film capacitors have mostly been replaced by polyester film capacitors as of 2012. However, some manufacturers may still offer PS film capacitors in their production program, backed by large amounts of polystyrene film stocked in their warehouse. Polystyrene capacitors have an important advantage - they have a temperature coefficient near zero and so are useful in tuned circuits where drift with temperature must be avoided.
Polycarbonate (PC) film capacitors Polycarbonate film capacitors are film capacitors with a dielectric made of the polymerized esters of carbonic acid and dihydric alcohols polycarbonate (PC), sometimes given the trademarked name Makrofol. They are manufactured as wound metallized as well as film/foil types. These capacitors have a low dissipation factor and because of their relatively temperature-independent electrical properties of about ±80 ppm over the entire temperature range, they had many applications for low-loss and temperature-stable applications such as timing circuits, precision analog circuits, and signal filters in applications with tough environmental conditions. PC film capacitors had been manufactured since the mid-1950s, but the main supplier of polycarbonate film for capacitors had ceased the production of this polymer in film form as of the year 2000. As a result, most of the manufacturers of polycarbonate film capacitors worldwide had to stop their production of PC film capacitors and changed to polypropylene film capacitors instead.
Paper (film) capacitors (MP) and mixed film capacitors File:MP-Power-Capacitor-Construction.svg|MP capacitor, single-sided metallized paper (additional layer of paper to cover pinhole defects), windings impregnated with insulating oil File:MPK-Power-Capacitor-Construction.svg|MKP power capacitor, single-sided metallized paper and polypropylene film, (mixed dielectric), windings impregnated with insulating oil File:MKV-Power-Capacitor-Construction.svg|MKV power capacitor, double-sided metallized paper (field-free mechanical carrier of the electrodes), polypropylene film (dielectric), windings impregnated with insulating oil Historically, the first "film" type capacitors were paper capacitors of film/foil configuration. They were fairly bulky, and not particularly reliable. As of 2012, paper is used in the form of metallized paper for MP capacitors with self-healing properties used for EMI suppression. Paper is also used as an insulating mechanical carrier of metallized-layer electrodes, and combined with polypropylene dielectric, mostly in power capacitors rated for high current AC and high voltage DC applications. Paper as carrier of the electrodes has the advantages of lower cost and somewhat better adherence of metallization to paper than to polymer films. But paper alone as dielectric in capacitors is not reliable enough for the growing quality requirements of modern applications. The combination of paper together with polypropylene film dielectric is a cost-effective way to improve quality and performance. The better adhering of metallization on paper is advantageous especially at high current pulse loads, and the polypropylene film dielectric increases the voltage rating. However, the roughness of a metallized paper surface can cause many small air-filled bubbles between the dielectric and the metallization, decreasing the breakdown voltage of the capacitor. For this reason, larger film capacitors or power capacitors using paper as carrier of the electrodes usually are filled with an insulating oil or gas, to displace the air bubbles for a higher breakdown voltage. However, since almost every major manufacturer offers its own proprietary film capacitors with mixed film materials, it is difficult to give a universal and general overview of the specific properties of mixed film capacitors.
Other plastic film capacitors Other plastic materials than those described above may be used as the dielectric in film capacitors. Thermoplastic polymers such as
Polyimide (PI),
Polyamide (PA, better known as Nylon or Perlon),
Polyvinylidene fluoride (PVDF),
Siloxane,
Polysulfone (PEx) and Aromatic Polyester (FPE) are described in the technical literature as possible dielectric films for capacitors. The primary reason for considering new film materials for capacitors is the relative low
permittivity of commonly used materials. With a higher permittivity, film capacitors could be made even smaller, an advantage in the market for more-compact portable electronic devices. In 1984, a new film capacitor technology that makes use of vacuum-deposited electron-beam cross-linked
acrylate materials as dielectric in film capacitors was announced as a patent in the press. But as of 2012, only one manufacturer markets a specific acrylate SMD film capacitor, as an X7R MLCC replacement. Polyimide (PI), a thermoplastic polymer of
imide monomers, is proposed for film capacitors called Polyimide-, PI- or Kapton capacitors. Kapton is the trade name of polyimide from
DuPont. This material is of interest because its high temperature resistance up to 400 °C. But as of 2012, no specific PI capacitor series
film capacitors have been announced. The offered film capacitor, Kapton CapacitorCL11, announced from "dhgate" is a "Type: Polypropylene Film Capacitor". Another very strange Kapton capacitor can be found at YEC, a Chinese producer of capacitors. Here the announced "Kapton capacitors" are in reality
supercapacitors, a completely different technology. Perhaps the Kapton film in these supercapacitors is used as a separator between the electrodes of this
double-layer capacitor. Kapton films are often offered as an adhesive film for the outer insulation of capacitor packages.
Polyvinylidene fluoride (PVDF) has a very high permittivity of 18 to 20, which allows large amounts of energy to be stored in a small space (
volumetric efficiency). However, it has a
Curie temperature of only 60 °C, which limits its usability. Film capacitors with PVDF are described for one very special application, in portable
defibrillators. As of 2012, for all the other mentioned materials such as PA, PVDF, Siloxane, PEx or FPE, specific series of film capacitors with these plastic films are not known to be produced in commercial quantities. == Standardization of film capacitors ==