Spall

Mechanical spalling occurs at high-stress contact points, for example, in a ball bearing. Spalling occurs in preference to brinelling, where the maximal shear stress occurs not at the surface, but just below, shearing the spall off. One of the simplest forms of mechanical spalling is plate impact, in which two waves of compression are reflected on the free-surfaces of the plates and then interact to generate a region of high tensile stress inside one of the plates. Spalling can also occur as an effect of cavitation, where fluids are subjected to localized low pressures that cause vapour bubbles to form, typically in pumps, water turbines, vessel propellers, and even piping under some conditions. When such bubbles collapse, a localized high pressure can cause spalling on adjacent surfaces. Anti-tank warfare s "X" turret during the Battle of Jutland on display at the Torpedo Bay Navy Museum in Auckland. Caption reads, "The chunk of armour plating you see here was gouged out of X turret by a German shell." In anti-tank warfare, spalling through mechanical stress is an intended effect of high-explosive squash head (HESH) anti-tank shells and many other munitions, which may not be powerful enough to pierce the armour of a target. The relatively soft warhead, containing or made of plastic explosive, flattens against the armour plating on tanks and other armoured fighting vehicles (AFVs) and explodes, creating a shock wave that travels through the armour as a compression wave and is reflected at the free surface as a tensile wave breaking (tensile stress/strain fracture) the metal on the inside. The resulting spall is dangerous to crew and equipment, and may result in a partial or complete disablement of a vehicle and/or its crew. Many AFVs are equipped with spall liners inside their armour for protection. A kinetic energy penetrator, if it can defeat the armour, generally causes spalling within the target as well, which helps to destroy or disable the vehicle and its crew. An early example of anti-tank weapon intentionally designed to cause spallation instead of penetration is the wz. 35 anti-tank rifle. ==Spalling in mechanical weathering==

of dunite boulder Spalling is a common mechanism of rock weathering, and occurs at the surface of a rock when there are large shear stresses under the surface. This form of mechanical weathering can be caused by freezing and thawing, unloading, thermal expansion and contraction, or salt deposition. Unloading Unloading is the release of pressure due to the removal of an overburden. When the pressure is reduced rapidly, the rapid expansion of the rock causes high surface stress and spalling. Freeze–thaw weathering Freeze–thaw weathering is caused by moisture freezing inside cracks in rock. Upon freezing its volume expands, causing large forces which cracks spall off the outer surface. As this cycle repeats the outer surface repeatedly undergoes spalling, resulting in weathering. Some stone and masonry surfaces used as building surfaces will absorb moisture at their surface. If exposed to severe freezing conditions, the surface may flake off due to the expansion of the water. This effect can also be seen in terracotta surfaces (even if glazed) if there is an entrance for water at the edges. Exfoliation Exfoliation (or onion skin weathering) is the gradual removing of spall due to the cyclic increase and decrease in the temperature of the surface layers of the rock. Rocks do not conduct heat well, so when they are exposed to extreme heat, the outermost layer becomes much hotter than the rock underneath causing differential thermal expansion. This differential expansion causes sub-surface shear stress, in turn causing spalling. Extreme temperature change, such as forest fires, can also cause spalling of rock. This mechanism of weathering causes the outer surface of the rock to fall off in thin fragments, sheets or flakes, hence the name exfoliation or onion skin weathering. Salt spalling Salt spalling is a specific type of weathering which occurs in porous building materials, such as brick, natural stone, tiles and concrete. Dissolved salt is carried through the material in water and crystallizes inside the material near the surface as the water evaporates. As the salt crystals expand this builds up shear stresses which break away spall from the surface. ==Corrosion==

In corrosion, spalling occurs when a substance (metal or concrete) sheds tiny particles of corrosion products as the corrosion reaction progresses. Although they are not soluble or permeable, these corrosion products do not adhere to the parent material's surface to form a barrier to further corrosion, as happens in passivation. Spallation happens as the result of a large volume change during the reaction. In the case of actinide metals (most notably the depleted uranium used in some types of ammunition), the material expands so strongly upon exposure to air that a fine layer of oxide is forcibly expelled from the surface. A slowly oxidised plug of metallic uranium can sometimes resemble an onion subjected to desquamation. The main hazard however arises from the pyrophoric character of actinide metals which can spontaneously ignite when their specific area is high. This property, along with the inherent toxicity and (for some to a lesser extent) radioactivity of these elements, make them dangerous to handle in metallic form under air. Therefore, they are often handled under an inert atmosphere (nitrogen or argon) inside an anaerobic glovebox. ==Spalling in refractory concrete==

There are two drivers for spalling of concrete: thermal strain caused by rapid heating and internal pressures due to the removal of water. Being able to predict the outcome of different heating rates on thermal stresses and internal pressure during water removal is particularly important to industry and other concrete structures. Explosive spalling events of refractory concrete can result in serious problems. If an explosive spalling occurs, projectiles of reasonable mass (1–10 kg) can be thrust violently over many metres, which will have safety implications and render the refractory structure unfit for service. Repairs will then be required resulting in significant costs to industry. ==Anatomical spalling in blast injuries==

Blast-wave overpressure from explosions can cause spalling in the human body where the wave travels across the interface between denser to less-dense areas of anatomy. This is notable at the boundary between liquid and air, for example from the bowel wall to a gas-filled bowel, or from lung tissue to cavity. Spallation, implosion, and shearing are the three primary mechanisms known to cause blast injuries. == See also ==