𝔰𝔲(2) and 𝔰𝔬(3) The algebra \mathfrak{su}(2) of the
special unitary group SU(2) is three-dimensional, with generators given by the
Pauli matrices . The generators of the group SU(2) satisfy the commutation relations (where \varepsilon^{abc} is the
Levi-Civita symbol): [\sigma_a, \sigma_b] = 2 i \varepsilon^{abc} \sigma_c where \sigma_1 = \begin{pmatrix} 0 & 1 \\ 1 & 0 \end{pmatrix},~~ \sigma_2 = \begin{pmatrix} 0 & -i \\ i & 0 \end{pmatrix},~~ \sigma_3 = \begin{pmatrix} 1 & 0 \\ 0 & -1 \end{pmatrix} In this case, the structure constants are {{tmath|1= f^{abc} = 2 i \varepsilon^{abc} }}. Note that the constant 2
i can be absorbed into the definition of the basis vectors; thus, defining , one can equally well write [t_a, t_b] = \varepsilon^{abc} t_c . Doing so emphasizes that the Lie algebra \mathfrak{su}(2) of the Lie group SU(2) is isomorphic to the Lie algebra \mathfrak{so}(3) of
SO(3). This brings the structure constants into line with those of the
rotation group SO(3). That is, the commutator for the
angular momentum operators are then commonly written as [L_i, L_j] = \varepsilon^{ijk} L_k where L_x = L_1 = \begin{pmatrix} 0 & 0 & 0 \\ 0 & 0 & -1 \\ 0 & 1 & 0 \end{pmatrix},~~ L_y = L_2 = \begin{pmatrix} 0 & 0 & 1 \\ 0 & 0 & 0 \\ -1 & 0 & 0 \end{pmatrix},~~ L_z = L_3 = \begin{pmatrix} 0 & -1 & 0 \\ 1 & 0 & 0 \\ 0 & 0 & 0 \end{pmatrix} are written so as to obey the
right hand rule for rotations in 3-dimensional space. The difference of the factor of 2
i between these two sets of structure constants can be infuriating, as it involves some subtlety. Thus, for example, the two-dimensional complex vector space can be given a
real structure. This leads to two inequivalent two-dimensional
fundamental representations of {{tmath| \mathfrak{su}(2) }}, which are isomorphic, but are
complex conjugate representations; both, however, are considered to be
real representations, precisely because they act on a space with a
real structure. In the case of three dimensions, there is only one three-dimensional representation, the
adjoint representation, which is a
real representation; more precisely, it is the same as its
dual representation, shown above. That is, one has that the
transpose is minus itself: {{tmath|1= L_k^\text{T} = -L_k }}. In any case, the Lie groups are considered to be real, precisely because it is possible to write the structure constants so that they are purely real.
𝔰𝔲(3) A less trivial example is given by
SU(3): Its generators,
T, in the defining representation, are: : T^a = \frac{\lambda^a }{2} , where , the
Gell-Mann matrices, are the SU(3) analog of the
Pauli matrices for SU(2): : These obey the relations : \left[T^a, T^b \right] = i f^{abc} T^c : \{T^a, T^b\} = \frac{1}{3}\delta^{ab} + d^{abc} T^c . The structure constants are totally antisymmetric. They are given by: : f^{123} = 1 \, : f^{147} = -f^{156} = f^{246} = f^{257} = f^{345} = -f^{367} = \frac{1}{2} : f^{458} = f^{678} = \frac{\sqrt{3}}{2} , and all other f^{abc} not related to these by permuting indices are zero. The
d take the values: : d^{118} = d^{228} = d^{338} = -d^{888} = \frac{1}{\sqrt{3}} : d^{448} = d^{558} = d^{668} = d^{778} = -\frac{1}{2\sqrt{3}} : d^{146} = d^{157} = -d^{247} = d^{256} = d^{344} = d^{355} = -d^{366} = -d^{377} = \frac{1}{2} .
𝔰𝔲(N) For the general case of 𝔰𝔲(N), there exists closed formula to obtain the structure constant, without having to compute commutation and anti-commutation relations between the generators. We first define the N^{2}-1 generators of 𝔰𝔲(N), based on a generalisation of the Pauli matrices and of the Gell-Mann matrices (using the bra-ket notation where |m\rangle\langle n| is the matrix unit). There are N(N-1)/2
symmetric matrices, : \hat{T}_{\alpha_{nm}}=\frac{1}{2}(|m\rangle\langle n|+|n\rangle\langle m|) , N(N-1)/2 anti-symmetric matrices, : \hat{T}_{\beta_{nm}}=-i\frac{1}{2}(|m\rangle\langle n|-|n\rangle\langle m|) , and N-1 diagonal matrices, : \hat{T}_{\gamma_{n}}=\frac{1}{\sqrt{2n(n-1)}}\Big(\sum_{l=1}^{n-1}|l\rangle\langle l|+(1-n)|n\rangle\langle n|)\Big) . To differenciate those matrices we define the following indices: : \alpha_{nm}=n^2+2(m-n)-1 , : \beta_{nm}=n^2+2(m-n) , : \gamma_{n}=n^2-1 , with the condition . All the non-zero totally anti-symmetric structure constants are : f^{\alpha_{nm}\alpha_{kn}\beta_{km}}=f^{\alpha_{nm}\alpha_{nk}\beta_{km}}=f^{\alpha_{nm}\alpha_{km}\beta_{kn}}=\frac{1}{2} , : f^{\beta_{nm}\beta_{km}\beta_{kn}}=\frac{1}{2} , : f^{\alpha_{nm}\beta_{nm}\gamma_{m}}=-\sqrt{\frac{m-1}{2m}},~f^{\alpha_{nm}\beta_{nm}\gamma_{n}}=\sqrt{\frac{n}{2(n-1)}} , : f^{\alpha_{nm}\beta_{nm}\gamma_{k}}=\sqrt{\frac{1}{2k(k-1)}},~m All the non-zero totally symmetric structure constants are : d^{\alpha_{nm}\alpha_{kn}\alpha_{km}}=d^{\alpha_{nm}\beta_{kn}\beta_{km}}=d^{\alpha_{nm}\beta_{mk}\beta_{nk}}=\frac{1}{2} , : d^{\alpha_{nm}\beta_{nk}\beta_{km}}=-\frac{1}{2} , : d^{\alpha_{nm}\alpha_{nm}\gamma_{m}}=d^{\beta_{nm}\beta_{nm}\gamma_{m}}=-\sqrt{\frac{m-1}{2m}} , : d^{\alpha_{nm}\alpha_{nm}\gamma_{k}}=d^{\beta_{nm}\beta_{nm}\gamma_{k}}=\sqrt{\frac{1}{2k(k-1)}},~m : d^{\alpha_{nm}\alpha_{nm}\gamma_{n}}=d^{\beta_{nm}\beta_{nm}\gamma_{n}}=\frac{2-n}{\sqrt{2n(n-1)}} , : d^{\alpha_{nm}\alpha_{nm}\gamma_{k}}=d^{\beta_{nm}\beta_{nm}\gamma_{k}}=\sqrt{\frac{2}{k(k-1)}},~n : d^{\gamma_{n}\gamma_{k}\gamma_{k}}=\sqrt{\frac{2}{n(n-1)}},~k : d^{\gamma_{n}\gamma_{n}\gamma_{n}}=(2-n)\sqrt{\frac{2}{n(n-1)} .} For more details on the derivation see and.{{cite journal |title=Non-adiabatic mapping dynamics in the phase space of the SU(N) Lie group == Examples from other algebras ==