The
lachrymatory agent (
Z)-butanethial
S-oxide, along with several 1-butenyl
thiosulfinates have been detected in crushed plant material by
mass spectrometry using a
DART ion source. (
Z)-Butanethial
S-oxide (the higher homolog of
syn-propanethial-S-oxide, the onion lachrymatory agent) isolated from the plant was shown to be identical to a synthetic sample. The precursor to the active lachrymatory compound, (RS,RC)-(
E)-
S-(1-butenyl) cysteine
S-oxide (homoiso
alliin), was isolated from
A. siculum, and a closely related species,
Allium tripedale, and fully characterized.
A. siculum is unpalatable to grazing animals such as deer and, akin to garlic (
Allium sativum), may be toxic to cats and dogs, likely owing to the sulfur compounds discussed above. == References ==