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Suboxide

Suboxides are a class of oxides wherein the electropositive element is in excess relative to the “normal” oxides. When the electropositive element is a metal, the compounds are sometimes referred to as “metal-rich”. Thus the normal oxide of caesium is Cs2O, which is described as a Cs+ salt of O2−. A suboxide of caesium is Cs11O3, where the charge on Cs is clearly less than 1+, but the oxide is still described as O2−. Suboxides typically feature extensive bonding between the electropositive element, often leading to clusters.

Metal-containing suboxides
Suboxides are intermediates along the pathway that forms the normal oxide. Suboxides are sometimes visible when certain metals are exposed to small amounts of O2: :22 Cs + 3 O2 → 2 Cs11O3 :4 Cs11O3 + 5 O2 → 22 Cs2O Several suboxides of caesium and rubidium have been characterized by X-ray crystallography. As of 1997, the inventory includes the following Rb9O2, Rb6O, Cs11O3, Cs4O, Cs7O, Cs11O3Rb, Cs11O3Rb2, and Cs11O3Rb3. ==Carbon suboxide==
Carbon suboxide
The suboxide of carbon adopts an unremarkable structure. As for related organic cumulenes (e.g. ketene), C3O2 obeys the octet rule. ==Related compounds==
Related compounds
Subnitrides are also known. For example, Na16Ba6N features a nitride-centered octahedral cluster of six barium atoms embedded in a matrix of sodium. ==References==
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