Spectrum s judge workpiece temperatures by the colour of the glow. Black-body radiation has a characteristic, continuous
frequency spectrum that depends only on the body's temperature, called the Planck spectrum or
Planck's law. The spectrum is peaked at a characteristic frequency that shifts to higher frequencies with increasing temperature, and at
room temperature most of the emission is in the
infrared region of the
electromagnetic spectrum. As the temperature increases past about 500 degrees
Celsius, black bodies start to emit significant amounts of visible light. Viewed in the dark by the human eye, the first faint glow appears as a "ghostly" grey (the visible light is actually red, but low intensity light activates only the eye's grey-level sensors). With rising temperature, the glow becomes visible even when there is some background surrounding light: first as a dull red, then yellow, and eventually a "dazzling bluish-white" as the temperature rises. When the body appears white, it is emitting a substantial fraction of its energy as
ultraviolet radiation. The
Sun, with an
effective temperature of approximately 5800 K, is an approximate black body with an emission spectrum peaked in the central, yellow-green part of the
visible spectrum, but with significant power in the ultraviolet as well. Black-body radiation provides insight into the
thermodynamic equilibrium state of cavity radiation.
Black body Most types of matter emit electromagnetic radiation while at a temperature above
absolute zero. The radiation represents a conversion of a body's
internal energy into electromagnetic energy, and is therefore called
thermal radiation. It is a
spontaneous process of radiative distribution of
entropy. Conversely, all normal matter absorbs electromagnetic radiation to some degree. An object that absorbs all radiation falling on it, at all
wavelengths, is called a black body. When a black body is at a uniform temperature, its emission has a characteristic frequency distribution that depends on the temperature. Its emission is called black-body radiation. The concept of the black body is an idealization, as perfect black bodies do not exist in nature. However,
graphite and
lamp black, with emissivities greater than 0.95, are good approximations to a black material. Experimentally, black-body radiation may be established best as the ultimately stable steady state equilibrium radiation in a cavity in a rigid body, at a uniform temperature, that is entirely opaque and is only partly reflective. Black-body radiation has the unique absolutely stable distribution of radiative intensity that can persist in thermodynamic equilibrium in a cavity. For a black body (a perfect absorber) there is no reflected radiation, and so the spectral radiance is entirely due to emission. In addition, a black body is a diffuse emitter (its emission is independent of direction). Black-body radiation becomes a visible glow of light if the temperature of the object is high enough. The
Draper point is the temperature at which all solids glow a dim red, about . At , a small opening in the wall of a large uniformly heated opaque-walled cavity (such as an oven), viewed from outside, looks red; at , it looks white. No matter how the oven is constructed, or of what material, as long as it is built so that almost all light entering is absorbed by its walls, it will contain a good approximation to black-body radiation. The spectrum, and therefore color, of the light that comes out will be a function of the cavity temperature alone. A graph of the spectral radiation intensity plotted versus frequency(or wavelength) is called the
black-body curve. Different curves are obtained by varying the temperature. lava flow can be estimated by observing its color. The result agrees well with other measurements of temperatures of lava flows at about . When the body is black, the absorption is obvious: the amount of light absorbed is all the light that hits the surface. For a black body much bigger than the wavelength, the light energy absorbed at any wavelength
λ per unit time is strictly proportional to the black-body curve. This means that the black-body curve is the amount of light energy emitted by a black body, which justifies the name. This is the condition for the applicability of
Kirchhoff's law of thermal radiation: the black-body curve is characteristic of thermal light, which depends only on the
temperature of the walls of the cavity, provided that the walls of the cavity are completely opaque and are not very reflective, and that the cavity is in
thermodynamic equilibrium. When the black body is small, so that its size is comparable to the wavelength of light, the absorption is modified, because a small object is not an efficient absorber of light of long wavelength, but the principle of strict equality of emission and absorption is always upheld in a condition of thermodynamic equilibrium. In the laboratory, black-body radiation is approximated by the radiation from a small hole in a large cavity, a
hohlraum, in an entirely opaque body that is only partly reflective, that is maintained at a constant temperature. This technique leads to the alternative term
cavity radiation. Any light entering the hole would have to reflect off the walls of the cavity multiple times before it escaped, in which process it is nearly certain to be absorbed. Absorption occurs regardless of the
wavelength of the radiation entering (as long as it is small compared to the hole). The hole, then, is a close approximation of a theoretical black body and, if the cavity is heated, the
spectrum of the hole's radiation (that is, the amount of light emitted from the hole at each wavelength) will be continuous, and will depend only on the temperature and the fact that the walls are opaque and at least partly absorptive, but not on the particular material of which they are built nor on the material in the cavity (compare with
emission spectrum). The
radiance or observed intensity is not a function of direction. Therefore, a black body is a perfect
Lambertian radiator. Real objects never behave as full-ideal black bodies, and instead the emitted radiation at a given frequency is a fraction of what the ideal emission would be. The
emissivity of a material specifies how well a real body radiates energy as compared with a black body. This emissivity depends on factors such as temperature, emission angle, and wavelength. However, it is typical in engineering to assume that a surface's spectral emissivity and absorptivity do not depend on wavelength so that the emissivity is a constant. This is known as the
gray body assumption. image (2012) of the
cosmic microwave background radiation across the universe. With non-black surfaces, the deviations from ideal black-body behavior are determined by both the surface structure, such as roughness or granularity, and the chemical composition. On a "per wavelength" basis, real objects in states of
local thermodynamic equilibrium still follow
Kirchhoff's Law: emissivity equals absorptivity, so that an object that does not absorb all incident light will also emit less radiation than an ideal black body; the incomplete absorption can be due to some of the incident light being transmitted through the body or to some of it being reflected at the surface of the body. In
astronomy, objects such as
stars are frequently regarded as black bodies, though this is often a poor approximation. An almost perfect black-body spectrum is exhibited by the
cosmic microwave background radiation.
Hawking radiation is the hypothetical black-body radiation emitted by
black holes, at a temperature that depends on the mass, charge, and spin of the hole. If this prediction is correct, black holes will very gradually shrink and evaporate over time as they lose mass by the emission of photons and other particles. A black body radiates energy at all frequencies, but its intensity rapidly tends to zero at high frequencies (short wavelengths). For example, a black body at room temperature () with one square meter of surface area will emit a photon in the visible range (390–750 nm) at an average rate of one photon every 41 seconds, meaning that, for most practical purposes, such a black body does not emit in the visible range. The study of the laws of black bodies and the failure of classical physics to describe them helped establish the foundations of
quantum mechanics.
Additional explanations According to the classical theory of radiation, if each
Fourier mode of the equilibrium radiation (in an otherwise empty cavity with perfectly reflective walls) is considered as a degree of freedom capable of exchanging energy, then, according to the
equipartition theorem of classical physics, there would be an equal amount of energy in each mode. Since there are an infinite number of modes, this would imply infinite
heat capacity, as well as a nonphysical (i.e. not real) spectrum of emitted radiation that grows without bound with increasing frequency, predicting infinite emission power. The problem is known as the
ultraviolet catastrophe. Moreover, the classical theory cannot explain the experimentally observed peak in emission spectra (see also
Wien's law). Instead, in the quantum treatment of this problem, the numbers of the energy modes are
quantized, attenuating the spectrum at high frequency in agreement with experimental observation and resolving the catastrophe. The modes that had more energy than the thermal energy of the substance itself were not considered, and because of quantization modes having infinitesimally little energy were excluded. Thus for shorter wavelengths very few modes (having energy more than h \nu) were allowed, supporting the data that the energy emitted is reduced for wavelengths less than the wavelength of the observed peak of emission. Notice that there are two factors responsible for the shape of the graph, which can be seen as working opposite to one another. Firstly, shorter wavelengths have a larger number of modes associated with them. This accounts for the increase in spectral radiance as one moves from the longest wavelengths towards the peak at relatively shorter wavelengths. Secondly, though, at shorter wavelengths more energy is needed to reach the threshold level to occupy each mode: the more energy needed to excite the mode, the lower the probability that this mode will be occupied. As the wavelength decreases, the probability of exciting the mode becomes exceedingly small, leading to fewer of these modes being occupied: this accounts for the decrease in spectral radiance at very short wavelengths, left of the peak. Combined, they give the characteristic graph. Calculating the black-body curve was a major challenge in
theoretical physics during the late nineteenth century. The problem was solved in 1901 by
Max Planck in the formalism now known as
Planck's law of black-body radiation. By making changes to
Wien's radiation law (not to be confused with Wien's displacement law) consistent with
thermodynamics and
electromagnetism, he found a mathematical expression fitting the experimental data satisfactorily. Planck had to assume that the energy of the oscillators in the cavity was quantized, which is to say that it existed in integer multiples of some quantity.
Einstein built on this idea and proposed the quantization of electromagnetic radiation itself in 1905 to explain the
photoelectric effect. These theoretical advances eventually resulted in the superseding of classical electromagnetism by
quantum electrodynamics. These quanta were called
photons and the black-body cavity was thought of as containing a
gas of photons. In addition, it led to the development of quantum probability distributions, called
Fermi–Dirac statistics and
Bose–Einstein statistics, each applicable to a different class of particles,
fermions and
bosons. The wavelength at which the radiation is strongest is given by Wien's displacement law, and the overall power emitted per unit area is given by the
Stefan–Boltzmann law. So, as temperature increases, the glow color changes from red to yellow to white to blue. As the peak wavelength moves into the ultra-violet and further on, a tail of the spectrum will remain in the visible range and even will increase its intensity, appearing blue. It will never become invisible—indeed, the radiation of visible light increases
monotonically with temperature. The Stefan–Boltzmann law says that the total radiant heat power emitted from a surface of a black body is proportional to the fourth power of its
absolute temperature. The law was formulated by Josef Stefan in 1879 and later derived by
Ludwig Boltzmann. The formula is given, where
E is the radiant heat emitted from a unit of area per unit time (power emitted from a unit area),
T is the absolute temperature, and is the
Stefan–Boltzmann constant. ==Equations==