Terminal alkene

There are two types of alpha-olefins, branched and linear (or normal). The chemical properties of branched alpha-olefins with a branch at either the second (vinylidene) or the third carbon number are significantly different from the properties of linear alpha-olefins and those with branches on the fourth carbon number and further from the start of the chain. Examples of linear alpha-olefins are propene, but-1-ene and dec-1-ene. An example of a branched alpha-olefin is isobutylene. ==Production==

A variety of methods are employed for production of alpha-olefins. One class of methods starts with ethylene which is either dimerized or oligomerized. These conversions are respectively effected by the alphabutol process, giving 1-butene, and the Shell higher olefin process which gives a range of alpha-olefins. The former is based on titanium-based catalysts, and the latter relies on nickel-based catalysts. A whole other approach to alpha-olefins, especially long chain derivatives, involves cracking of waxes: : In the PACOL process (paraffin conversion to olefins), linear alkanes are dehydrogenated over a platinum-based catalyst. ==Applications==

Alpha-olefins are valued building blocks for other industrial chemicals. A major portion of medium or long chain derivatives are converted to detergents and plasticizers. A common first step in making such products is hydroformylation followed by hydrogenation of the resulting aldehydes. Long chain alpha-olefins are also oligomerized to give medium molecular weight oils that serve as lubricants. Alkylation of benzene with alpha-olefins followed by ring-sulfonation gives linear alkylbenzene sulfonates (LABS) which are biodegradable detergents. Competing often with these petroleum-derived products are derivatives of fatty acids, such as fatty alcohols and fatty amines. Low molecular weight alpha-olefins (butenes, hexenes, etc.) are used as comonomers, which are incorporated into polyethylene. Some are subjected to olefin metathesis as a route to propylene. ==See also==